C₂₃H₂₇N₃O₄S

Base Information

• Chemical Name: C₂₃H₂₇N₃O₄S
• CAS No.: 1310050-47-5
• Molecular Formula: C₂₃H₂₇N₃O₄S
• Molecular Weight: 441.551
• Mol file: 1310050-47-5.mol

Synonyms:C₂₃H₂₇N₃O₄S

Chemical Property of C₂₃H₂₇N₃O₄S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₂₇N₃O₄S

There total 5 articles about C₂₃H₂₇N₃O₄S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

C16H21N3O4S (1310050-46-4) + benzyl bromide (100-39-0) → C23H27N3O4S (1310050-47-5)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 - 20 ℃;

DOI:10.1021/jo1025157

Reference yield:

para-thiocresol (106-45-6) → C23H27N3O4S (1310050-47-5)

Guidance literature:

Multi-step reaction with 4 steps

1.1: boron trifluoride diethyl etherate / chloroform / 0 - 40 °C

2.1: sodium methylate / methanol / 0.5 h / 20 °C

2.2: Amberlite IR-120H(+) resin

3.1: camphor-10-sulfonic acid / 24 h / 20 °C / Inert atmosphere

3.2: Reflux

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 - 20 °C

With camphor-10-sulfonic acid; boron trifluoride diethyl etherate; sodium methylate; sodium hydride; In methanol; chloroform; N,N-dimethyl-formamide; mineral oil;

DOI:10.1021/jo1025157

Reference yield:

p-tolyl 2-deoxy-2-azido-1-thio-α/β-D-galactopyranoside → C23H27N3O4S (1310050-47-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: camphor-10-sulfonic acid / 24 h / 20 °C / Inert atmosphere

1.2: Reflux

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 - 20 °C

With camphor-10-sulfonic acid; sodium hydride; In N,N-dimethyl-formamide; mineral oil;

DOI:10.1021/jo1025157

upstream raw materials:

C₁₆H₂₁N₃O₄S

benzyl bromide

1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-D-galactopyranose

para-thiocresol

Downstream raw materials:

3,4-di-O-acetyl-2-azido-6-O-benzyl-2-deoxy-α-D-galactopyranose 1-O-trichloroacetimidate

C₄₅H₄₅N₃O₁₅

C₂₄H₂₇N₃O₆S