9-N-PROPYLFLUORENE

Base Information

• Chemical Name: 9-N-PROPYLFLUORENE
• CAS No.: 4037-45-0
• Molecular Formula: C16H16
• Molecular Weight: 208.3
• Hs Code.: 2902909090
• Mol file: 4037-45-0.mol

Synonyms:Fluorene,9-propyl- (6CI,7CI,8CI); 9-Propylfluorene

Chemical Property of 9-N-PROPYLFLUORENE

Chemical Property:

• PSA: 0.00000
• LogP: 4.59900

Purity/Quality:

98%min ^*data from raw suppliers

9-Propylfluorene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 9-Propylfluorene has been used in the preparation of Ter- and quater-phenyls which exhibit strongly efficient fluorescence.

Technology Process of 9-N-PROPYLFLUORENE

There total 7 articles about 9-N-PROPYLFLUORENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9H-fluorene (86-73-7) + 1-iodo-propane (107-08-4) → 9-propyl-9H-fluorene (4037-45-0)

Guidance literature:

9H-fluorene; With n-butyllithium; In tetrahydrofuran; hexane; at 20 ℃; for 1.5h;

1-iodo-propane; In tetrahydrofuran; hexane; at 20 ℃; for 2h; Further stages.;

DOI:10.1002/chem.200601142

Reference yield: 100.0%

→ 9-propyl-9H-fluorene (4037-45-0)

Guidance literature:

Reference yield: 78.0%

propan-1-ol (71-23-8) + 9H-fluorene (86-73-7) → 9-propyl-9H-fluorene (4037-45-0)

Guidance literature:

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; potassium tert-butylate; In toluene; at 120 ℃; for 18h; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.9b02913

upstream raw materials:

9H-fluorene

9-propylidene-fluorene

1-iodo-propane

9-fluorenone

Downstream raw materials:

2-bromo-9,9-dipropyl-7-(4-methoxyphenyl)fluorene

9,9-dipropyl-2-(4-methoxyphenyl)fluorene

8-{4-[5-(7-{5-[4-(8-hydroxy-octyloxy)-phenyl]-thiophen-2-yl}-9,9-dipropyl-9H-fluoren-2-yl)-thiophen-2-yl]-phenoxy}-octan-1-ol

C₃₉H₃₄O₂S₂

Refernces

• 1、 -. "New cyclopentadienyl, indenyl or fluorenyl substituted phosphine compounds and their use in catalytic reactions". Page/Page column 34. . Retrieved 2008/06/13.
• 2、 Contoret, Adam,Farrar, Simon,Jackson, Perregrin,Kelly, Stephen M.,Khan, Sultan,Nicholls, Edward,Oneill, Mary,Richards, Gary. "Electroluminescent nematic polymer networks with polarised emission". . p. 511 - 518. Retrieved 2007/10/03.