(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

Base Information

Chemical Name:(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane
CAS No.:177573-86-3
Molecular Formula:C₁₅H₂₁BO₂
Molecular Weight:244.142
Hs Code.:
DSSTox Substance ID:DTXSID60571180
Nikkaji Number:J724.904G,J3.230.905D
Wikidata:Q82458810

Synonyms:177573-86-3;(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane;4,4,5,5-tetramethyl-2-[(E)-3-phenylprop-1-enyl]-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-[(1E)-3-phenyl-1-propen-1-yl]-;DTXSID60571180;MFCD22189433;EN300-802033;G67449;4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane;1,3,2-Dioxaborolane,4,4,5,5-tetramethyl-2-[(1E)-3-phenyl-1-propen-1-yl]-;4,4,5,5-Tetramethyl-2-[(1E)-3-phenylprop-1-en-1-yl]-1,3,2-dioxaborolane

Suppliers and Price of (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:244.1634601
Heavy Atom Count:18
Complexity:288

Purity/Quality:: 98%+ ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C=CCC2=CC=CC=C2
Isomeric SMILES:B1(OC(C(O1)(C)C)(C)C)/C=C/CC2=CC=CC=C2

Technology Process of (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

There total 24 articles about (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 947-91-1
Diphenylacetaldehyde

: 78782-17-9
4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane

: 177573-86-3
(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

Guidance literature:: 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane; With 2,2,6,6-tetramethylpiperidinyl-lithium; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

Diphenylacetaldehyde; In tetrahydrofuran; at 0 - 20 ℃; for 16.1667h; Inert atmosphere; Schlenk technique;
DOI:10.1039/d1cc05815k

Reference yield: 87.0%

: 10147-11-2
propargyl benzene

: 73183-34-3
bis(pinacol)diborane

: 177573-86-3
(E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane

Guidance literature:: With [bis(acetoxy)iodo]benzene; sodium t-butanolate; In ethanol; at 20 ℃; for 12h; regioselective reaction;
DOI:10.1039/c7ra03680a