tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

Base Information

Chemical Name:tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate
CAS No.:214141-73-8
Molecular Formula:BF₄*C₂₄H₁₇BiCl₃
Molecular Weight:707.543
Hs Code.:

Synonyms:tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

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Chemical Property of tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

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Technology Process of tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

There total 3 articles about tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 13755-29-8
sodium tetrafluoroborate

: 121899-91-0
tris(4-chlorophenyl)bismuth difluoride

: 98-80-6
phenylboronic acid

: 214141-73-8
tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; water; stirring (room temp., 2 h), NaBF4 soln. (H2O) addn., stirring (30 min); extg. (CH2Cl2), drying (MgSO4), filtering, evapn. (reduced pressure), crystn. (Et2O / CH2Cl2 = 10 : 1);
DOI:10.1021/om9804531

Reference yield: 95.0%

: 13755-29-8
sodium tetrafluoroborate

: 121899-91-0
tris(4-chlorophenyl)bismuth difluoride

: 109-63-7
trifluoroborane diethyl ether

: 98-80-6
phenylboronic acid

: 214141-73-8
tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

Guidance literature:: In dichloromethane; water; Ar-atmosphere; addn. of BF3*OEt2 (1 equiv.) to soln. of Bi-compd. (1 equiv.) and B-compd. (1 equiv.) at 0°C, stirring (2 h, room temp.), addn. of NaBF4 (excess, in H2O), stirring (20 min); phase sepn., water phase extn. (CH2Cl2), org. phase drying (MgSO4), chromy. (SiO2), evapn. (vac.), crystn. (Et2O/CH2Cl2 10/1); elem. anal.;
DOI:10.1021/om990597v

Reference yield:

: 5575-51-9
tris(4-chlorophenyl)bismuthane

: 214141-73-8
tris(4-chlorophenyl)phenylbismuthonium tetrafluoroborate

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: water; dichloromethane

In dichloromethane; water;
DOI:10.1021/om990597v