(S)-12-bromo-4-hydroxy[2.2]paracyclophane

Base Information

Chemical Name:(S)-12-bromo-4-hydroxy[2.2]paracyclophane
CAS No.:5628-21-7
Molecular Formula:C₁₆H₁₅BrO
Molecular Weight:303.198
Hs Code.:

Synonyms:(S)-12-bromo-4-hydroxy[2.2]paracyclophane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-12-bromo-4-hydroxy[2.2]paracyclophane

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Technology Process of (S)-12-bromo-4-hydroxy[2.2]paracyclophane

There total 1 articles about (S)-12-bromo-4-hydroxy[2.2]paracyclophane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 196316-30-0,196316-31-1,23927-40-4,96392-77-7
4,16-dibromo[2.2]paracyclophane

: 5628-11-5,157018-15-0
4-hydroxy-[2,2]-paracyclophane

: 5628-21-7
(S)-12-bromo-4-hydroxy[2.2]paracyclophane

Guidance literature:: 4,16-dibromo[2.2]paracyclophane; With n-butyllithium; In diethyl ether; hexane; at 20 ℃; for 4.5h;

With Trimethyl borate; In diethyl ether; hexane; at 20 ℃;

With dihydrogen peroxide; sodium hydroxide; In diethyl ether; hexane; water; at 20 ℃; for 1h;
DOI:10.1002/ejoc.201403316

Reference yield: 75.0%

: 5628-21-7
(S)-12-bromo-4-hydroxy[2.2]paracyclophane

: 637-44-5
phenylpropyolic acid

: C₂₅H₁₉BrO₂

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1021/acs.joc.8b02773

Reference yield: 53.0%

: 98-88-4
benzoyl chloride

: 5628-21-7
(S)-12-bromo-4-hydroxy[2.2]paracyclophane

: 1238382-35-8
12-bromo[2.2]paracyclophan-4-yl benzoate

: 1238382-34-7
[13-bromo-5-hydroxy[2.2]paracyclophan-4-yl]phenylmethanone

Guidance literature:: (S)-12-bromo-4-hydroxy[2.2]paracyclophane; With titanium tetrachloride; In dichloromethane; at 20 ℃; for 1.5h;

benzoyl chloride; In dichloromethane; at 20 ℃; for 168h;
DOI:10.1016/j.tetasy.2010.03.038