[NBu₄][(C₆F₅)₂Pt(μ-PPh₂)₂Pd(8-hydroxyquinolinate)]

Base Information

• Chemical Name: [NBu₄][(C₆F₅)₂Pt(μ-PPh₂)₂Pd(8-hydroxyquinolinate)]
• CAS No.: 1430209-75-8
• Molecular Formula: C₁₆H₃₆N*C₄₂H₂₄F₁₀NO₂P₂PdPt
• Molecular Weight: 1370.56
• Mol file: 1430209-75-8.mol

Synonyms:[NBu₄][(C₆F₅)₂Pt(μ-PPh₂)₂Pd(8-hydroxyquinolinate)]

Chemical Property of [NBu₄][(C₆F₅)₂Pt(μ-PPh₂)₂Pd(8-hydroxyquinolinate)]

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of [NBu₄][(C₆F₅)₂Pt(μ-PPh₂)₂Pd(8-hydroxyquinolinate)]

There total 1 articles about [NBu₄][(C₆F₅)₂Pt(μ-PPh₂)₂Pd(8-hydroxyquinolinate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

2-Picolinic acid (98-98-6) + (NBu4)2{(pentafluorophenyl)2platinum(II)(μ-diphenylphosphido)2palladium(II)(μ-Cl)2palladium(II)(μ-diphenylphosphido)2platinum(II)(pentafluorophenyl)2} → [NBu4][(C6F5)2Pt(μ-PPh2)2Pd(8-hydroxyquinolinate)] (1430209-75-8)

Guidance literature:

(NBu4)2{(pentafluorophenyl)2platinum(II)(μ-diphenylphosphido)2palladium(II)(μ-Cl)2palladium(II)(μ-diphenylphosphido)2platinum(II)(pentafluorophenyl)2}; With silver perchlorate; In acetone; for 1h; Darkness;

2-Picolinic acid; In acetone; for 0.5h;

With tetra(n-butyl)ammonium hydroxide; In methanol; acetone; for 0.5h;

DOI:10.1021/ic4004005

Reference yield: 53.0%

[NBu4][(C6F5)2Pt(μ-PPh2)2Pd(8-hydroxyquinolinate)] (1430209-75-8) + iodine (7553-56-2,12190-71-5,8031-47-8) → [NBu4][(PPh2-pic)(C6F5)Pt(μ-I)(μ-PPh2)Pd(C6F5)]

Guidance literature:

In dichloromethane; at 20 ℃; for 20h; Inert atmosphere;

DOI:10.1021/ic4004005

Reference yield: 36.0%

triphenylphosphinesilver perchlorate + [NBu4][(C6F5)2Pt(μ-PPh2)2Pd(8-hydroxyquinolinate)] (1430209-75-8) → [(C6F5)2Pt(μ-PPh2)2Pd((picolinate)AgPPh3)]

Guidance literature:

In dichloromethane; for 0.5h;

DOI:10.1002/ejic.201300808

upstream raw materials:

2-Picolinic acid