Iodozinc(1+) 3-methylbenzen-1-ide

Base Information

Chemical Name:Iodozinc(1+) 3-methylbenzen-1-ide
CAS No.:312693-24-6
Molecular Formula:C7H7 I Zn
Molecular Weight:283.427
Hs Code.:2931900090
DSSTox Substance ID:DTXSID30394308
Mol file:312693-24-6.mol

Synonyms:Iodozinc(1+) 3-methylbenzen-1-ide;iodozinc(1+);methylbenzene;312693-24-6;DTXSID30394308

Suppliers and Price of Iodozinc(1+) 3-methylbenzen-1-ide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3-Methylphenylzinc iodide solution 0.5M in THF
50ml
$ 157.00

Rieke Metals
3-Methylphenylzinciodide
100mL
$ 448.00

Rieke Metals
3-Methylphenylzinciodide
50mL
$ 263.00

American Custom Chemicals Corporation
3-METHYLPHENYLZINC IODIDE 95.00%
1L
$ 7969.50

American Custom Chemicals Corporation
3-METHYLPHENYLZINC IODIDE 95.00%
500ML
$ 5313.00

American Custom Chemicals Corporation
3-METHYLPHENYLZINC IODIDE 95.00%
100ML
$ 2783.55

Alfa Aesar
3-Methylphenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
50ml
$ 138.00

Total 8 raw suppliers

Chemical Property of Iodozinc(1+) 3-methylbenzen-1-ide

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:g/cm³
LogP:2.67840
Sensitive.:Air Sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:281.88839
Heavy Atom Count:9
Complexity:138

Purity/Quality:

99% ^*data from raw suppliers

3-Methylphenylzinc iodide solution 0.5M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xn
Statements: 14-19-22-36/38-40-36/37-11
Safety Statements: 16-26-33-36-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1=CC=C[C-]=C1.[Zn+]I

Technology Process of Iodozinc(1+) 3-methylbenzen-1-ide

There total 1 articles about Iodozinc(1+) 3-methylbenzen-1-ide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 625-95-6
3-Iodotoluene

: 7440-66-6
zinc

: 312693-24-6
m-tolylzinc(II) iodide

Guidance literature:: zinc; With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; In tetrahydrofuran; at 20 ℃; for 0.0833333h; Schlenk technique; Glovebox;

3-Iodotoluene; In tetrahydrofuran; for 24h; Schlenk technique; Glovebox; Reflux;
DOI:10.1021/jacs.8b09401

Reference yield: 91.0%

: 312693-24-6
m-tolylzinc(II) iodide

: 201230-82-2
carbon monoxide

: 2852-68-8
3,3'-dimethylbenzophenone

Guidance literature:: carbon monoxide; With 1,1'-bis-(diphenylphosphino)ferrocene; chloro(1,5-cyclooctadiene)rhodium(I) dimer; In tetrahydrofuran; at 20 ℃; for 0.166667h; under 760.051 Torr;

m-tolylzinc(II) iodide; With ethylene dibromide; In tetrahydrofuran; at 60 ℃; for 3h;
DOI:10.1021/jo1025173

Reference yield: 78.0%

: 312693-24-6
m-tolylzinc(II) iodide

: 124-38-9,18923-20-1
carbon dioxide

: 99-04-7
m-Toluic acid

Guidance literature:: m-tolylzinc(II) iodide; carbon dioxide; With lithium chloride; In N,N-dimethyl-formamide; at 50 ℃; for 24h; under 760.051 Torr;

With hydrogenchloride; water; In N,N-dimethyl-formamide;
DOI:10.1021/ol900528h