trans-{(PPh₃)2Pt(CNC₆H₁₁)Cl}BF₄

Base Information

• Chemical Name: trans-{(PPh₃)2Pt(CNC₆H₁₁)Cl}BF₄
• CAS No.: 110313-80-9
• Molecular Formula: BF₄*C₄₃H₄₁ClNP₂Pt
• Molecular Weight: 951.09
• Mol file: 110313-80-9.mol

Synonyms:trans-{(PPh₃)2Pt(CNC₆H₁₁)Cl}BF₄

Chemical Property of trans-{(PPh₃)2Pt(CNC₆H₁₁)Cl}BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-{(PPh₃)2Pt(CNC₆H₁₁)Cl}BF₄

There total 1 articles about trans-{(PPh₃)2Pt(CNC₆H₁₁)Cl}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

sodium tetrafluoroborate (13755-29-8) + trans-dichlorobis(triphenylphosphine)platinum(II) (14056-88-3) + Cyclohexyl isocyanide (931-53-3) → trans-{(PPh3)2Pt(CNC6H11)Cl}BF4 (110313-80-9) + sodium chloride (7647-14-5)

Guidance literature:

In acetone; under inert gas; dropwise addn. of the isocyanide in acetone to the suspn. of the Pt complex in acetone in presence of NaBF4 at room temp.; stirring for 1 h; solvent removed, residue dissolved in CH2Cl2; soln. filtered and concd., addn. of Et2O yields the solid; elem. anal.;

Reference yield: 80.0%

hexafluoroacetone sesquihydrate + PtCl(P(C6H5)3)2(CNC6H11)(1+)*BF4(1-)=PtCl(P(C6H5)3)2(CNC6H11)(BF4) (110313-80-9) → [Pt(Cl)(C(=O)NHC6H11)(PPh3)2]

Guidance literature:

With triethylamine; In dichloromethane; addn. of amine and ketone to a soln. of Pt complex in CH2Cl2, standing in the dark for 1 d; evapn. in vac., recrystn. (CH2Cl2/acetone, Et2O); elem. anal.;

DOI:10.1002/zaac.200700540

upstream raw materials:

sodium tetrafluoroborate

trans-dichlorobis(triphenylphosphine)platinum(II)

Cyclohexyl isocyanide

Refernces