2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

Base Information

Chemical Name:2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane
CAS No.:1644527-00-3
Molecular Formula:C₁₆H₂₄BBrO₂
Molecular Weight:339.08
Hs Code.:

Synonyms:2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

Suppliers and Price of 2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 4 raw suppliers

Chemical Property of 2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

Chemical Property:

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

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Technology Process of 2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

There total 2 articles about 2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 3972-64-3
1-bromo-3-(tertbutyl)benzene

: 73183-34-3
bis(pinacol)diborane

: 1644527-00-3
2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

Guidance literature:: With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; In n-heptane; at 60 ℃; for 8h; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.201404436

Reference yield:

: 61676-62-8
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 129316-09-2
1,3-dibromo-5-t-butylbenzene

: 1644527-00-3
2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

Guidance literature:: 1,3-dibromo-5-t-butylbenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2h; Inert atmosphere;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere;
DOI:10.1039/c5tc01449b

Reference yield:

: 1644527-00-3
2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane

: 1123172-38-2
1-bromo-3-(tert-butyl)-5-fluorobenzene

Guidance literature:: 2-(3-bromo--5-(tert-butyl)phenyl)--4,4,5,5--tetramethyl--1,3,2-dioxaborolane; With potassium tert-butylate; In methanol; at 20 ℃; for 2h; Inert atmosphere;

With silver trifluoromethanesulfonate; In acetone; at 0 ℃; for 0.5h; Inert atmosphere;

In acetone; at 20 ℃; for 1h; Inert atmosphere; Molecular sieve;
DOI:10.1002/anie.201404436