4-(Phenoxymethyl)phenylboronic acid

Base Information

Chemical Name:4-(Phenoxymethyl)phenylboronic acid
CAS No.:397843-61-7
Molecular Formula:C₁₃H₁₃BO₃
Molecular Weight:228.055
Hs Code.:2931900090
DSSTox Substance ID:DTXSID50449703
Wikidata:Q82269221
Mol file:397843-61-7.mol

Synonyms:4-(phenoxymethyl)phenylboronic acid;397843-61-7;(4-(Phenoxymethyl)phenyl)boronic acid;[4-(phenoxymethyl)phenyl]boronic Acid;(4-(Phenoxymethyl)phenyl)boronicacid;SCHEMBL177615;DTXSID50449703;XQA84361;MFCD09966155;AKOS005974755;BS-28176;CS-0174664;FT-0717301;F77563;4-(phenoxymethyl)phenylboronic acid, AldrichCPR

Suppliers and Price of 4-(Phenoxymethyl)phenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-(Phenoxymethyl)phenylboronicAcid
50mg
$ 45.00

Crysdot
(4-(Phenoxymethyl)phenyl)boronicacid 95+%
5g
$ 564.00

Chemenu
(4-(Phenoxymethyl)phenyl)boronicacid 98%
1g
$ 179.00

American Custom Chemicals Corporation
4-(PHENOXYMETHYL)PHENYLBORONIC ACID 95.00%
1G
$ 289.80

American Custom Chemicals Corporation
4-(PHENOXYMETHYL)PHENYLBORONIC ACID 95.00%
5G
$ 1430.96

Alichem
(4-(Phenoxymethyl)phenyl)boronicacid
5g
$ 627.00

AK Scientific
4-(Phenoxymethyl)phenylboronicacid
1g
$ 251.00

Total 12 raw suppliers

Chemical Property of 4-(Phenoxymethyl)phenylboronic acid

Chemical Property:

PSA：49.69000
LogP:0.94540
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:228.0957744
Heavy Atom Count:17
Complexity:209

Purity/Quality:

98% ^*data from raw suppliers

4-(Phenoxymethyl)phenylboronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=C(C=C1)COC2=CC=CC=C2)(O)O

Technology Process of 4-(Phenoxymethyl)phenylboronic acid

There total 3 articles about 4-(Phenoxymethyl)phenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 68162-47-0
4-bromomethylphenylboronic acid

: 139-02-6
sodium phenoxide

: 397843-61-7
[4-(phenoxymethyl)phenyl]boronic acid

Guidance literature:: 4-bromomethylphenylboronic acid; With N,N-diethanolaminomethyl polystyrene; In dichloromethane; at 20 ℃;

sodium phenoxide; With tetra-(n-butyl)ammonium iodide; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 24h;

In tetrahydrofuran; water; at 20 ℃; Further stages.;
DOI:10.1021/jo0106501

Reference yield: 20.0%

: 397843-61-7
[4-(phenoxymethyl)phenyl]boronic acid

Guidance literature:

Reference yield:

: 108-95-2,27073-41-2
phenol

: 397843-61-7
[4-(phenoxymethyl)phenyl]boronic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / 1-methyl-pyrrolidin-2-one / 0.5 h / 0 °C

2.1: N,N-diethanolaminomethyl polystyrene / CH₂Cl₂ / 20 °C

2.2: n-Bu₄NI / 1-methyl-pyrrolidin-2-one / 24 h / 20 °C

2.3: 61 percent / tetrahydrofuran; H₂O / 20 °C

With N,N-diethanolaminomethyl polystyrene; sodium hydride; In 1-methyl-pyrrolidin-2-one; dichloromethane;
DOI:10.1021/jo0106501