1-adamantyl hydroperoxide

Base Information

• Chemical Name: 1-adamantyl hydroperoxide
• CAS No.: 128530-59-6
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.236
• Mol file: 128530-59-6.mol

Synonyms:1-adamantyl hydroperoxide

Chemical Property of 1-adamantyl hydroperoxide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1-adamantyl hydroperoxide

There total 3 articles about 1-adamantyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione (91233-19-1) → 2-(adamantan-1-yl)pyridine + 2-((3s,5s,7s)-adamantan-1-ylthio)pyridine (54476-11-8) + 4-(1-adamantyl)pyridine (60159-38-8) + 1-adamanthanol (768-95-6) + 1-Adamantanecarboxylic acid (828-51-3) + 1-adamantyl hydroperoxide (128530-59-6)

Guidance literature:

With oxygen; In pyridine; acetic acid; for 2h; Product distribution; Ambient temperature; Irradiation; various oxygen pressure;

DOI:10.1021/ja00200a037

Reference yield: 9.0%

1,2,4,5-tetracyanobenzene (712-74-3) + adamantane (281-23-2) → 2-Adamantanone (700-58-3) + 1-adamanthanol (768-95-6) + 1-adamantyl hydroperoxide (128530-59-6) + 5-(adamantan-1-yl)benzene-1,2,4-tricarbonitrile

Guidance literature:

With oxygen; In acetonitrile; Quantum yield; Mechanism; Irradiation;

DOI:10.1039/c39950000041

Reference yield:

adamantane (281-23-2) → 2-Adamantanone (700-58-3) + 1-adamantyl hydroperoxide (128530-59-6) + adamantyl 2-hydroperoxide

Guidance literature:

With sodium decatungstate; oxygen; In acetonitrile; Quantum yield; Product distribution; Mechanism; Irradiation; other alkanes; other decatungstates; other solvents;

upstream raw materials:

1-(adamantane-1-carbonyloxy)pyridine-2(1H)-thione

1,2,4,5-tetracyanobenzene

adamantane

Refernces

• 1、 Mella, Mariella,Freccero, Mauro,Albini, Angelo. "Photoinduced SET for the Functionalization of Alkanes". . p. 41 - 42. Retrieved 2007/10/02.