1-(4'-bromobiphenyl-4-yl)-ferrocene

Base Information

Chemical Name:1-(4'-bromobiphenyl-4-yl)-ferrocene
CAS No.:284688-05-7
Molecular Formula:C₂₂H₁₇BrFe
Molecular Weight:417.128
Hs Code.:

Synonyms:1-(4'-bromobiphenyl-4-yl)-ferrocene

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Chemical Property of 1-(4'-bromobiphenyl-4-yl)-ferrocene

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Technology Process of 1-(4'-bromobiphenyl-4-yl)-ferrocene

There total 2 articles about 1-(4'-bromobiphenyl-4-yl)-ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1274-09-5
bis(ferrocenyl)mercury

: 105946-82-5
4-bromo-4'-iodobiphenyl

: 284688-05-7
1-(4'-bromobiphenyl-4-yl)-ferrocene

Guidance literature:: With NaI; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; acetone; Fe-complex, ligand and NaI in THF and acetone were placed under Ar, mixt. heated to boiling, Pd-complex was added, refluxed for 1.5 h; filtered, evapd. in vac., column chromy. with benzene-hexane; elem. anal.;
DOI:10.1016/S0022-328X(01)00979-2

Reference yield: 32.0%

: 102-54-5,55404-68-7
ferrocene

: 81793-62-6
4'-bromo-biphenyldiazonium tetrafluoroborate

: 284688-05-7
1-(4'-bromobiphenyl-4-yl)-ferrocene

Guidance literature:: In acetic acid; 1,2-dichloro-ethane; trifluoroacetic acid; portionwise addn. of diazonium salt to a soln. of ferrocene in a mixt. of dichloroethane, acetic acid, trifluoroacetic acid at 20°C during 1 h, stirring for 4 h, keeping at this temp. for 12 h; addn. of water and chloroform, sepn. of organic layer, extn. of aq. layer with chloroform, washing the soln. with soln. of ascorbic acid, drying, evapn., chromy. (aluminum oxide, light petroleum followed with 1:3 benzene-light petroleum); elem. anal.;
DOI:10.1023/A:1023998420937

Reference yield: 68.0%

: 284688-05-7
1-(4'-bromobiphenyl-4-yl)-ferrocene

: 5720-05-8
4-methylphenylboronic acid

: 401845-50-9
4-ferrocenyl-4''-methyl-[1,1';4',1'']terphenyl

Guidance literature:: With K₂CO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; water; Fe-complex, ligand, K2CO3 were dissolved in THF and water under Ar, Pd-complex was added, stirred at reflux for 24 h; solvent was evapd. under vac., column chromy. on silica with benzene-hexane; elem. anal.;
DOI:10.1016/S0022-328X(01)00979-2