<2-(4,5-dihydrofuryl)>diphenylethoxysilane

Base Information

• Chemical Name: <2-(4,5-dihydrofuryl)>diphenylethoxysilane
• CAS No.: 144889-93-0
• Molecular Formula: C₁₈H₂₀O₂Si
• Molecular Weight: 296.441
• Mol file: 144889-93-0.mol

Synonyms:<2-(4,5-dihydrofuryl)>diphenylethoxysilane

Chemical Property of <2-(4,5-dihydrofuryl)>diphenylethoxysilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of <2-(4,5-dihydrofuryl)>diphenylethoxysilane

There total 1 articles about <2-(4,5-dihydrofuryl)>diphenylethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

ethanol (64-17-5) + <2-(4,5-dihydrofuryl)>diphenylsilane (130648-87-2) → <2-(4,5-dihydrofuryl)>diphenylethoxysilane (144889-93-0)

Guidance literature:

With sodium hydroxide; for 6h; Heating;

DOI:10.1016/0022-328X(92)85060-A

Reference yield: 71.0%

<2-(4,5-dihydrofuryl)>diphenylethoxysilane (144889-93-0) → (2-tetrahydrofuryl)diphenylethoxysilane (144889-96-3)

Guidance literature:

With hydrogen; palladium/alumina; In pentane; for 10h; under 760 Torr; Ambient temperature;

DOI:10.1016/0022-328X(92)85060-A

Reference yield:

<2-(4,5-dihydrofuryl)>diphenylethoxysilane (144889-93-0) → 1-oxa-2-sila-2,2-diphenylcyclohexane (17933-86-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 71 percent / H₂ / 5percent Pd/Al₂O₃ / pentane / 10 h / 760 Torr / Ambient temperature

2: 37 percent / LiAlH₄ / diethyl ether / 4 h / Heating

3: 59 percent / 5percent Pd/Al₂O₃ / hexane / 15 h / Ambient temperature

With palladium/alumina; lithium aluminium tetrahydride; hydrogen; palladium/alumina; In diethyl ether; hexane; pentane;

DOI:10.1016/0022-328X(92)85060-A

upstream raw materials:

ethanol

<2-(4,5-dihydrofuryl)>diphenylsilane

Downstream raw materials:

(2-tetrahydrofuryl)diphenylethoxysilane

1-oxa-2-sila-2,2-diphenylcyclohexane

diphenyl(tetrahydrofuran-2-yl)silane