(±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

Base Information

Chemical Name:(±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one
CAS No.:1365839-71-9
Molecular Formula:C₂₇H₃₀N₄O₅S
Molecular Weight:522.625
Hs Code.:

Synonyms:(±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

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Chemical Property of (±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

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Technology Process of (±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

There total 13 articles about (±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: (±)-(2E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-ol

: 1365839-71-9
(±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1002/chem.201300292

Reference yield: 100.0%

: 1365839-70-8
C₂₇H₃₂N₄O₅S

: 1365839-71-9
(±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

Guidance literature:: With Dess-Martin periodane; In dichloromethane;
DOI:10.1016/j.tetlet.2012.01.110

Reference yield:

: 1365839-67-3
(±)-(2E)-ethylthio-2-ethylidene-5-(p-toluenesulfonyl)oxy-3-(benzyloxymethyl)pentanoate

: 1365839-71-9
(±)-(3E)-2-(azidoethyl)-[1-(N-benzenesulfonylindole-2-yl)]-3-(pivaloyloxymethyl)-3-penten-1-one

Guidance literature:: Multi-step reaction with 8 steps

1: quinoline; triethylsilane; 1-hexene / dichloromethane; acetone

2: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0 °C

3: sodium azide / dimethyl sulfoxide

4: pyridine

5: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / pH 7.2 / aq. phosphate buffer

6: Dess-Martin periodane / dichloromethane

7: n-butyllithium / tetrahydrofuran

8: Dess-Martin periodane / dichloromethane

With pyridine; quinoline; triethylsilane; sodium tetrahydroborate; n-butyllithium; 1-hexene; sodium azide; cerium(III) chloride heptahydrate; Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide; acetone;
DOI:10.1016/j.tetlet.2012.01.110