1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene

Base Information

• Chemical Name: 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene
• CAS No.: 1443050-76-7
• Molecular Formula: C₃₃H₃₄N₂
• Molecular Weight: 458.646
• Mol file: 1443050-76-7.mol

Synonyms:1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene

Chemical Property of 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene

There total 3 articles about 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

(2E)-2-[(2,6-diisopropylphenyl)imino]acenaphthylen-1(2H)-one (187605-59-0) + 2,4,6-trimethylaniline (88-05-1) → 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene (1443050-76-7)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; at 110 ℃; for 9h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt00023k

Reference yield:

acenaphthene quinone (82-86-0) → 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene (1443050-76-7)

Guidance literature:

Multi-step reaction with 2 steps

1: formic acid / ethanol / 16 h / 60 °C

2: toluene-4-sulfonic acid / tetrahydrofuran / 17 h / Reflux; Molecular sieve

With formic acid; toluene-4-sulfonic acid; In tetrahydrofuran; ethanol;

DOI:10.1080/00958972.2015.1057130

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) → 1-(2,6-diisopropylphenylimino)-2-(2,4,6-trimethylphenylimino)acenaphthylenylidene (1443050-76-7)

Guidance literature:

Multi-step reaction with 2 steps

1: formic acid / ethanol / 16 h / 60 °C

2: toluene-4-sulfonic acid / tetrahydrofuran / 17 h / Reflux; Molecular sieve

With formic acid; toluene-4-sulfonic acid; In tetrahydrofuran; ethanol;

DOI:10.1080/00958972.2015.1057130

upstream raw materials:

(2E)-2-[(2,6-diisopropylphenyl)imino]acenaphthylen-1(2H)-one

2,4,6-trimethylaniline

acenaphthene quinone

2,6-diisopropylbenzenamine

Downstream raw materials:

((2,6-diisopropylphenyl)imino)((2,4,6-trimethylphenyl)imino)acenaphthenenickel(II) dibromide