5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc

Base Information

• Chemical Name: 5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc
• CAS No.: 1010693-50-1
• Molecular Formula: C₅₄H₆₃BN₄O₂Zn
• Molecular Weight: 876.321
• Mol file: 1010693-50-1.mol

Synonyms:5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc

Chemical Property of 5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc

There total 7 articles about 5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

[10,20-bis-(3,5-di-tert-butylphenyl)-5,15-bis-bromoporphyrinato]zinc(II) (215313-78-3) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → {5,15-bis[3,5-di(tert-butyl)phenyl]-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1010693-50-1) + {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1039027-73-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In water; 1,2-dichloro-ethane; at 100 ℃; for 2h; Inert atmosphere;

DOI:10.1002/ejoc.201402634

Reference yield:

[5,15-bis(3',5'-di-tert-butylphenyl)-10-bromoporphyrinato]zinc(II) (294183-84-9) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → {5,15-bis[3,5-di(tert-butyl)phenyl]-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1010693-50-1)

Guidance literature:

With bis(triphenylphosphine)palladium(II) dichloride; triethylamine; In methanol; chloroform; 1,2-dichloro-ethane; at 90 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ol201303h

Reference yield:

(5-bromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) (294183-84-9) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 5,15-di(3,5-di-tert-butyl)phenyl-10-(44,55-tetramethyl-1,3,2-dioxaborolan-2-yl)porphinatozinc (1010693-50-1)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In 1,2-dichloro-ethane; at 90 ℃;

DOI:10.1016/j.jphotochem.2010.09.001

upstream raw materials:

(5-bromo-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

[5,15-bis(3',5'-di-tert-butylphenyl)-10-bromoporphyrinato]zinc(II)

Downstream raw materials:

C₁₁₀H₁₂₂N₈Zn₂

C₈₂H₇₇N₅O₂Zn

C₈₆H₇₄N₈NiZn

zinc(II) 5-(4-bromophenyl)-10,20-bis(3,5-di-tert-butylphenyl)porphyrin