4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

Base Information

Chemical Name:4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene
CAS No.:1379793-98-2
Molecular Formula:C₅₄H₆₇BF₂N₄O₁₂
Molecular Weight:1012.95
Hs Code.:

Synonyms:4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

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Chemical Property of 4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

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Technology Process of 4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

There total 3 articles about 4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 2510-23-8
3-Ethynylpyridine

: 1379793-96-0
4,4'-difluoro-2,6-diiodo-1,3,5,7-tetramethyl-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

: 1379793-98-2
4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; In tetrahydrofuran; at 60 ℃; for 14h; Inert atmosphere;
DOI:10.1002/ejoc.201101839

Reference yield:

: 625-82-1
2,4-dimethyl-1H-pyrrole

: 1379793-98-2
4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

Guidance literature:: Multi-step reaction with 3 steps

1.1: trifluoroacetic acid / dichloromethane / 18 h / 20 °C / Inert atmosphere

1.2: 1.5 h / Inert atmosphere

1.3: 0 - 20 °C / Inert atmosphere

2.1: iodine; iodic acid / ethanol; water / 2 h / 20 °C / Inert atmosphere

3.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / tetrahydrofuran / 14 h / 60 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iodine; iodic acid; diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; ethanol; dichloromethane; water; 3.1: Sonogashira coupling;
DOI:10.1002/ejoc.201101839

Reference yield:

: 866122-72-7
3,4,5-tris-{2-[2-(2-methoxy-ethoxy)-ethoxy]-ethoxy}-benzaldehyde

: 1379793-98-2
4,4'-difluoro-1,3,5,7-tetramethyl-2,6-bis(3-pyridylethynyl)-8-(3,4,5-tris{2-[2-(2-methoxyethoxy)ethoxy]ethoxy})-4-bora-3a,4a-diaza-s-indacene

Guidance literature:: Multi-step reaction with 3 steps

1.1: trifluoroacetic acid / dichloromethane / 18 h / 20 °C / Inert atmosphere

1.2: 1.5 h / Inert atmosphere

1.3: 0 - 20 °C / Inert atmosphere

2.1: iodine; iodic acid / ethanol; water / 2 h / 20 °C / Inert atmosphere

3.1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; diisopropylamine / tetrahydrofuran / 14 h / 60 °C / Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iodine; iodic acid; diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; ethanol; dichloromethane; water; 3.1: Sonogashira coupling;
DOI:10.1002/ejoc.201101839