Iron tetracarbonyl hydride

Base Information

Chemical Name:Iron tetracarbonyl hydride
CAS No.:12002-28-7
Molecular Formula:C₄H₂FeO₄
Molecular Weight:169.904
Hs Code.:
Wikidata:Q4456631
Mol file:12002-28-7.mol

Synonyms:Iron tetracarbonyl hydride;Q4456631

Suppliers and Price of Iron tetracarbonyl hydride

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Iron tetracarbonyl hydride

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:169.930244
Heavy Atom Count:9
Complexity:10

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[FeH2]

Technology Process of Iron tetracarbonyl hydride

There total 11 articles about Iron tetracarbonyl hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 78465-74-4
(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾*(CO)4FeSi(CH₃)3^(1-)=(C₆H₅)3PNP(C₆H₅)3[(CO)4FeSi(CH₃)3]

: 1493-13-6
trifluorormethanesulfonic acid

: 71564-37-9,22763-20-8,12002-28-7
dihydridotetracarbonyliron

: 993-07-7
trimethylsilan

: 63022-27-5
(CO)4FeH(Si(CH₃)3)

Guidance literature:: With Hexamethylbenzene; In dichloromethane-d2; mixt. of Fe-complex, hexamethylbenzene standard (molar ratio 1:0.25) and CD2Cl2 cooled to -40°C, 1 equiv of CF3SO3H added; without isolation; monitored by (1)H NMR spectra;

Reference yield:

: 56791-54-9
bis(triphenylphosphine)iminium tetracarbonylhydridoferrate⁽⁰⁾

: 71564-37-9,22763-20-8,12002-28-7
dihydridotetracarbonyliron

Guidance literature:: With hydrogenchloride; In further solvent(s); anhyd. HCl condensed at liquid N2 temp. into NMR tube contg. suspn. of (PPN)(HFe(CO)4) in methylcyclohexane-d14, tube sealed, agitated in dry ice/acetone bath; NMR examination;

Reference yield:

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 71564-37-9,22763-20-8,12002-28-7
dihydridotetracarbonyliron

Guidance literature:: With hydrogen; In gas; Irradiation (UV/VIS); irradn. of react. mixt. by laser light (337 nm); not isolated, detected by IR;
DOI:10.1021/ja00260a004