ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside
CAS No.:1316823-05-8
Molecular Formula:C₂₃H₂₃NO₇S
Molecular Weight:457.504
Hs Code.:

Synonyms:ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

There total 1 articles about ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 501088-85-3
ethyl 2-amino-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

: 98-88-4
benzoyl chloride

: 1316823-05-8
ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: In pyridine; at 0 ℃; for 1h; Cooling with ice;
DOI:10.1016/j.carres.2011.03.036

Reference yield: 89.0%

: 1316823-05-8
ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

: 75-36-5
acetyl chloride

: 1316823-07-0
ethyl 2-acetamido-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 ℃; for 1.5h; Cooling with ice;
DOI:10.1016/j.carres.2011.03.036

Reference yield:

: 1316823-05-8
ethyl 2-amino-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-1-thio-β-D-glucopyranoside

: 1316823-22-9
p-nitrophenyl 2-acetamido-4,6-di-O-benzoyl-2,3-N,O-carbonyl-2-deoxy-β-D-glucopyranosyl-(1->3)-2-azido-2-deoxy-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 1.5 h / 0 °C / Cooling with ice

2.1: 2,6-di-tert-butyl-4-methylpyridine / dichloromethane / 0.33 h / 20 °C / Inert atmosphere; Molecular sieve

2.2: 3 h / 0 - 20 °C / Inert atmosphere; Molecular sieve

3.1: water; acetic acid / dichloromethane / 12 h / 20 °C

With 2,6-di-tert-butyl-4-methylpyridine; water; acetic acid; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1016/j.carres.2011.03.036