(3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Base Information

Chemical Name:(3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane
CAS No.:1360444-51-4
Molecular Formula:C₂₃H₃₄O₃
Molecular Weight:358.521
Hs Code.:

Synonyms:(3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Suppliers and Price of (3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

There total 12 articles about (3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: C₃₀H₄₀O₅S

: 1360444-51-4
(3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Guidance literature:: With bis(diphenylphosphino)propanepalladium(II) dichloride; lithium triethylborohydride; In tetrahydrofuran; at 0 ℃; for 1.16667h;
DOI:10.1002/ejoc.201200631

Reference yield: 29.0%

: 1360444-49-0
1,3-dimethoxy-5-[(2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl]benzene

: 1360444-51-4
(3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Guidance literature:: With Shi's ketone;

Reference yield:

: 20469-65-2
1-bromo-3,5-dimethoxybenzene

: 1360444-51-4
(3S)-3-(3E,7E)-9-(3,5-dimethoxy-phenyl)-3,7-dimethyl-nona-3,7-dienyl-2,2-dimethyloxirane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran / 0.25 h / -78 °C

1.2: 0.17 h / -78 °C

1.3: -78 - 20 °C

2.1: (3aS,4'R,7aS)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolo-[4,5-c]pyran-6,4'-[1,3]dioxolan]-7(7aH)-one

With n-butyllithium; (3aS,4'R,7aS)-2,2,2',2'-tetramethyldihydrospiro[[1,3]dioxolo-[4,5-c]pyran-6,4'-[1,3]dioxolan]-7(7aH)-one; In tetrahydrofuran; 2.1: |Shi Asymmetric Epoxidation;
DOI:10.1002/ejoc.201200631