{Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

Base Information

Chemical Name:{Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄
CAS No.:109750-49-4
Molecular Formula:BF₄*C₅₂H₅₁FeP₄
Molecular Weight:942.524
Hs Code.:

{Fe(.eta2-H<sub>2</sub>)(H)(PPh<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)2}BF<sub>4</sub>

Synonyms:{Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

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Chemical Property of {Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

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Technology Process of {Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

There total 3 articles about {Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 47898-23-7
{Fe(H₂)(dppe)2}*C₇H₈

: 109750-49-4
{Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

Guidance literature:: In tetrahydrofuran; Tetrafluoroboric acid etherat was added dropwise to a filtered solution of Fe-compound in THF, microcrystals formed over 1h; evapn. under vacuum, cooled to -10°C, filtered;
DOI:10.1021/ja00206a009

Reference yield: 80.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: cis-{Fe(H)2(dppe)2} * 2C₇H₈

: 109750-49-4
{Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

Guidance literature:: In diethyl ether; dissoln. of Fe-complex in ether, dropwise addn. of HBF4*Et2O (excess) over a period of 1 min (stirring) to the suspn. (under 1 atm of Ar or H2, N2 not suitable); filtration, washing several times with diethyl ether;

Reference yield:

: 67969-82-8
tetrafluoroboric acid diethyl ether

: FeH(C₆H₄PPhCH₂CH₂PPh₂)(dppe)

: 109750-49-4
{Fe(.eta2-H₂)(H)(PPh₂CH₂CH₂PPh₂)2}BF₄

Guidance literature:: With H₂; In toluene; addn. of HBF4*Et2O to a soln. of Fe-complex in toluene at -5°C under H2, a purple ppt. is immediately formed but then turnes to a solid within 1 min;