tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron

Base Information

Chemical Name:tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron
CAS No.:120474-95-5
Molecular Formula:C₂₂H₁₉FeNO₅
Molecular Weight:433.244
Hs Code.:

Synonyms:tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron

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Chemical Property of tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron

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Technology Process of tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron

There total 1 articles about tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 79-37-8
oxalyl dichloride

: 2-((phenylamino)methyl)cyclopent-2-en-1-one

: 75765-29-6,51539-46-9,75765-30-9
[Fe(CO)3(η4-C6H7COOH)]

: 120474-95-5
tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron

Guidance literature:: With pyridine; In dichloromethane; benzene; to a CH2Cl2-soln. of Fe-complex (under Ar) was added oxalylchloride, stirred at room temp. for 3-6 h, excess oxalylchloride removed (vac.), oil dissolved in benzene, added pyridine and amine, mixt. stirred at room temp. for 16-24 h; diluted (Et2O), washed, dried over MgSO4, concd., chromy. (20% EtOAc/hexane);
DOI:10.1021/ja00193a023

Reference yield: 85.0%

: 120474-95-5
tricarbonyl{N-((5-oxocyclopentenyl)methyl)-N-phenyl-1-4-η-cyclohexa-1,3-dienecarboxamide}iron

: 120574-07-4,120474-87-5
tricarbonyl(1,2-dioxo-13-phenyl-13-azadispiro{4.0.5.3}tetradeca-7,9-diene)iron

Guidance literature:: With carbon monoxide; In further solvent(s); Bu2O-soln. of amide purged with CO for 1 min, refluxed for 6 h; cooled to room temp.; diluted (Et2O), filtered, concd.; TCL (20% EtOAc/hex); yielded an epimeric mixt.;
DOI:10.1021/ja00193a023