((chloro)2(phenyl)phosphane)pentacarbonylchromium

Base Information

Chemical Name:((chloro)2(phenyl)phosphane)pentacarbonylchromium
CAS No.:18461-40-0
Molecular Formula:C₁₁H₅Cl₂CrO₅P
Molecular Weight:371.033
Hs Code.:

Synonyms:((chloro)2(phenyl)phosphane)pentacarbonylchromium

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Chemical Property of ((chloro)2(phenyl)phosphane)pentacarbonylchromium

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Technology Process of ((chloro)2(phenyl)phosphane)pentacarbonylchromium

There total 1 articles about ((chloro)2(phenyl)phosphane)pentacarbonylchromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 644-97-3
Dichlorophenylphosphine

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 18461-40-0
((chloro)2(phenyl)phosphane)pentacarbonylchromium

Guidance literature:: With tetrahydrofuran; In toluene; Irradiation (UV/VIS); (N2); soln. of Cr(CO)6 and THF was irradiated for 24 h, then a less than equimolar amt. of P-ligand in toluene was added dropwise and mixt. was stirred for a few h; major part of solvent was evapd. and residue chromd. (alumina, toluene), crystals were obtained on cooling to -30°C;
DOI:10.1016/0022-2860(80)85261-6

Reference yield: 65.0%

: 18461-40-0
((chloro)2(phenyl)phosphane)pentacarbonylchromium

: 624-92-0
Dimethyldisulphide

: 90857-06-0
pentacarbonyl[bis(methylthio)phenylphospine]chromium

Guidance literature:: With cyclohexene; In dichloromethane; Electrolysis; under N2; cathode and anode - Pt, electrolyte - 0.3 M (Bu4N)Br/CH2Cl2, in anode room placed cyclohexene, in cathode - Cr complex and (MeS)2, cooled to -30 °C, potential of cathode was -1.7 V vs. SCE;
DOI:10.1016/0022-328X(84)80072-8

Reference yield: 30.0%

: 18461-40-0
((chloro)2(phenyl)phosphane)pentacarbonylchromium

: 4099-46-1
bis(trimethylsilyl)selenide

: 146687-45-8
{(((CO)5Cr)C₆H₅P)2Se₃}

Guidance literature:: In cyclohexane; addn. of Se compd. to stirred Cr complex soln. under N2; reacting, 10 d; evapn.; recrystn. (n-heptane or diethyl ether); crystn.; elem. anal.;