2H-Perfluoro(2-methylpentane)

Base Information

• Chemical Name: 2H-Perfluoro(2-methylpentane)
• CAS No.: 30320-28-6
• Molecular Formula: C6H F13
• Molecular Weight: 320.053
• Hs Code.: 2903499090
• European Community (EC) Number: 639-324-8
• DSSTox Substance ID: DTXSID90448210
• Wikidata: Q81985984
• Mol file: 30320-28-6.mol

Synonyms:2H-Perfluoro(2-methylpentane);30320-28-6;1,1,1,2,2,3,3,5,5,5-decafluoro-4-(trifluoromethyl)pentane;2H-Tridecafluoro-2-methylpentane;SCHEMBL5187478;DTXSID90448210;MFCD09763637;AKOS025310357;A820321;2-trifluoromethyl-1,1,1,3,3,4,4,5,5,5-decafluoropentane;1,1,1,2,2,3,3,5,5,5-decakis(fluoranyl)-4-(trifluoromethyl)pentane;Undecafluoro-2-(trifluoromethyl)pentane, 2-(Trifluoromethyl)-1,1,1,2,3,3,4,4,5,5,5-undecafluoropentane

Chemical Property of 2H-Perfluoro(2-methylpentane)

Chemical Property:

• Vapor Pressure: 153.667mmHg at 25°C
• Refractive Index: 1.253
• Boiling Point: 68.1°Cat760mmHg
• Flash Point: 5.4°C
• PSA: 0.00000
• Density: 1.608g/cm³
• LogP: 4.56010
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 13
• Rotatable Bond Count: 2
• Exact Mass: 319.9870661
• Heavy Atom Count: 19
• Complexity: 300

Purity/Quality:

97% ^*data from raw suppliers

2H-Perfluoro(2-methylpentane) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(C(F)(F)F)(F)F)(F)F)(C(F)(F)F)C(F)(F)F

Technology Process of 2H-Perfluoro(2-methylpentane)

There total 68 articles about 2H-Perfluoro(2-methylpentane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

perfluoro-2-methylpent-2-ene (1584-03-8) → 1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane (30320-28-6) + (E/Z)-3,3,3-trifluoro-1-pentafluoroethyl-2-trifluoromethylpropylidenehydrazine (124867-18-1)

Guidance literature:

With hydrazine hydrate; trifluoroacetic acid; In 1,2-dimethoxyethane; Ambient temperature;

DOI:10.1016/S0022-1139(00)80857-X

Reference yield: 85.0%

tris-dimethylamino-sulfonium; 1,1,1,3,3,4,4,5,5,5-decafluoro-2-trifluoromethyl-pentan-2-ide (100645-92-9) → 1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane (30320-28-6)

Guidance literature:

With Tetraethylene glycol dimethyl ether; trifluoroacetic acid; at -30 - 0 ℃; for 0.5h;

DOI:10.1021/ja00276a033

Reference yield: 71.4%

2-iodo-2-trifluoromethylperfluoropentane (102780-88-1) → perfluoro-2-methylpent-1-ene (359-72-8) + perfluoro-2-methylpent-2-ene (1584-03-8) + 1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane (30320-28-6)

Guidance literature:

With zinc; In acetic anhydride; for 3h; Product distribution; Ambient temperature;

DOI:10.1016/S0022-1139(00)82019-9

upstream raw materials:

perfluoro-2-methylpent-2-ene

4-pyridone

methanol

methyl bromide

Downstream raw materials:

2-perfluoromethyl-2-chloroperfluoropentane

3,3,4,4,5,5,5-heptafluoro-2,2-bis(trifluoromethyl)pentylbenzene

3,3,4,4,4-pentafluorobutan-2-one

(Z)-1,1,1,3,4,4,5,5,5-nonafluoropent-2-ene