Perfluoro-2-methyl-1-pentene

Base Information

• Chemical Name: Perfluoro-2-methyl-1-pentene
• CAS No.: 359-72-8
• Molecular Formula: C6F12
• Molecular Weight: 300.047
• DSSTox Substance ID: DTXSID101193695
• Mol file: 359-72-8.mol

Synonyms:perfluoro-2-methyl-1-pentene;SCHEMBL471746;JNMQNADSCUKNPR-UHFFFAOYSA-N;DTXSID101193695;359-72-8

Chemical Property of Perfluoro-2-methyl-1-pentene

Chemical Property:

• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 2
• Exact Mass: 299.9808379
• Heavy Atom Count: 18
• Complexity: 337

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(F)F)(C(C(C(F)(F)F)(F)F)(F)F)C(F)(F)F

Technology Process of Perfluoro-2-methyl-1-pentene

There total 19 articles about Perfluoro-2-methyl-1-pentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.4%

2-iodo-2-trifluoromethylperfluoropentane (102780-88-1) → perfluoro-2-methylpent-1-ene (359-72-8) + perfluoro-2-methylpent-2-ene (1584-03-8) + 1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane (30320-28-6)

Guidance literature:

With zinc; In acetic anhydride; for 3h; Product distribution; Ambient temperature;

DOI:10.1016/S0022-1139(00)82019-9

Reference yield: 63.5%

Hexafluoropropene oxide (428-59-1,25038-02-2) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) → perfluoro(2-propoxypropionyl) fluoride (2062-98-8,125037-08-3,75566-60-8) + perfluoro-2-methylpent-1-ene (359-72-8) + perfluoro-2-methylpentan-3-one (756-13-8) + perfluoro-4-methylpent-1-ene (287101-12-6)

Guidance literature:

With potassium fluoride; In diethylene glycol dimethyl ether;

DOI:10.1134/S1070427213030154

Reference yield:

1,1,1-trifluoro-3-iodopropane (460-37-7,71215-70-8) → 1,1,1-trifluoropropylene (677-21-4) + perfluoro-2-methylpent-1-ene (359-72-8) + 1,1,1,2,2,3,3,5,5,5-decafluoro-4-trifluoromethyl-pentane (30320-28-6)

Guidance literature:

With perfluoro-4-methyl-2-pentene; cesium fluoride; In N,N-dimethyl-formamide; at 60 ℃; for 18h;

DOI:10.1016/S0022-1139(00)81980-6

upstream raw materials:

methyl bromide

perfluoro-4-methyl-2-pentene

ethyl bromide

allyl iodid

Downstream raw materials:

2-perfluoromethyl-2-chloroperfluoropentane