2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester

Base Information

• Chemical Name: 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester
• CAS No.: 115852-17-0
• Molecular Formula: C₁₄H₁₆O₇
• Molecular Weight: 296.277
• Mol file: 115852-17-0.mol

Synonyms:2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester

Chemical Property of 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester

There total 3 articles about 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

methyl 2-methoxy-5-phenyl-furan-4-carboxylate (115852-14-7) → 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester (115852-17-0)

Guidance literature:

With oxygen; methylene blue; In methanol; Irradiation; 1.) -40 deg C, 120 min, 2.) 22 deg C, 30 min;

Reference yield:

methanol (67-56-1) + methyl 2-methoxy-5-phenyl-furan-4-carboxylate (115852-14-7) → 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester (115852-17-0)

Guidance literature:

With oxygen; methylene blue; at -40 ℃; for 2h; Yield given; Irradiation;

DOI:10.1055/s-1994-25610

Reference yield:

2-phenyl-4-methyl-5-methoxyoxazole (31698-99-4) → 2-Hydroperoxy-5,5-dimethoxy-2-phenyl-2,5-dihydro-furan-3-carboxylic acid methyl ester (115852-17-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 35 percent

2: 75 percent / O₂, Methylene Blue / methanol / Irradiation; 1.) -40 deg C, 120 min, 2.) 22 deg C, 30 min

With oxygen; methylene blue; In methanol;

upstream raw materials:

methanol

methyl 2-methoxy-5-phenyl-furan-4-carboxylate

2-phenyl-4-methyl-5-methoxyoxazole

Downstream raw materials:

(E)-2-benzoylbut-2-enedioic acid dimethyl ester