N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

Base Information

Chemical Name:N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex
CAS No.:1224969-64-5
Molecular Formula:C₂₀H₂₀BF₃NOPS
Molecular Weight:421.231
Hs Code.:

Synonyms:N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

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Chemical Property of N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

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Technology Process of N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

There total 2 articles about N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: N-benzyl-1,1,1-trifluoromethanesulfinamide

: 13292-87-0
dimethyl sulfide borane

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 1224969-64-5
N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; byproducts: H2; (N2), sulfinamide treated with dry THF, cooled to -78°C, treated with BuLi in hexanes, stirred for 15 min, treated dropwise with 1.2 equiv. of Ph2PC, stirred for 1 h, warmed to -30°C, treated with BH3*SMe2, stirred for 20 min; warmed to 0°C, treated with h2O and Et2O, aq. layer washed (Et2O), org. layer dried (MgSO4), filtered, concd.(vac.), chromy.(silica gel -hexane/EtOAc 80:20), elem. anal.;
DOI:10.1002/ejic.200900521

Reference yield:

: C₂₀H₁₇F₃NOPS

: 1224969-64-5
N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

Guidance literature:: With dimethylsulfide borane complex; In tetrahydrofuran; hexane; at -30 - 0 ℃; Inert atmosphere;
DOI:10.1002/ejic.200900521

Reference yield: 82.0%

: 57032-12-9
1-trimethylsilylacetylenehexacarbonyldicobalt

: 1224969-64-5
N-benzyl-N-diphenylphosphanyltrifluoromethylsulfinamide borane complex

: 1224969-68-9
dicobalttetracarbonyl(μ-trimethylsilylacetylene)(μ2-P,S-N-benzyl-trifluoromethylsulfinamide)

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; In toluene; (N2) borane protected sulfinamide, 1,4-diazabicyclo(2.2.2)octane and Co complex (1:1.1:1) treated with toluene, heated at 65°C for 5 h; concd.(vac.), chromy.(silica gel - hexanes/EtOH 95:5), elem. anal.;
DOI:10.1002/ejic.200900521