(η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II)

Base Information

• Chemical Name: (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II)
• CAS No.: 80298-82-4
• Molecular Formula: C₁₅H₂₇Cl₂PRu
• Molecular Weight: 410.329
• Mol file: 80298-82-4.mol

Synonyms:(η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II)

Chemical Property of (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II)

Chemical Property:

Purity/Quality:

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Technology Process of (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II)

There total 1 articles about (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

((η6-C6Me6)Ru(PMe3)(Cl)(NH2C6H5))BF4 (127133-20-4) → (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II) (80298-82-4) + ((η6-C6Me6)2diruthenium(μ-NHPh)3)BF4 + (η6-C6Me6ruthenium(PMe3)2)BF4 (127133-23-7)

Guidance literature:

With LiN(Si(CH₃)3)2; In tetrahydrofuran; hexane; cooling of a soln. of Ru-compd. in THF to -10°C (under Ar), addn. of LiN(SiMe3)2 in hexane, warming to room temp. stirring for ca. 12 h; filtn. and drying under reduced pressure, recrystn. from CH2Cl2/pentane, elem. anal. of anilide, THF-sol. portion contains mono- and diphhosphino-Ru-compd.;

Reference yield: 78.0%

(η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II) (80298-82-4) + aniline (62-53-3) → ((η6-C6Me6)Ru(PMe3)(Cl)(NH2C6H5))BF4 (127133-20-4)

Guidance literature:

With AgBF₄; In dichloromethane; byproducts: AgCl; addn. of a stirred suspn. of AgBF4 and aniline to a soln. of Ru-compd. (under Ar), stirring for 3 h; filtn., evapn. of solvent, washing with pentane and diethyl ether, drying under reduced pressure, recrystn. from CH2Cl2/diethyl ether, elem. anal.;

Reference yield: 75.0%

(η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II) (80298-82-4) + phenylmagnesium chloride (100-59-4) → C21H32ClPRu(1+)

Guidance literature:

In tetrahydrofuran; at -40 - 20 ℃;

DOI:10.1039/c4cc09699a

upstream raw materials:

((η6-C6Me6)Ru(PMe3)(Cl)(NH2C6H5))BF4

Downstream raw materials:

((η6-C6Me6)Ru(PMe3)(Cl)(NH2C6H5))BF4

{(C₆(CH₃)6)RuCl(P(CH₃)2(C₆H₅))P(CH₃)3}⁽¹⁺⁾*{PF₆}^(1-) = {(C₆(CH₃)6)RuCl(P(CH₃)2(C₆H₅))P(CH₃)3}{PF₆}