3-CYCLOHEXYL-2-METHYL-1-PROPENE

Base Information

• Chemical Name: 3-CYCLOHEXYL-2-METHYL-1-PROPENE
• CAS No.: 3990-93-0
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• Mol file: 3990-93-0.mol

Synonyms:Cyclohexane,(2-methyl-2-propenyl)- (9CI); Cyclohexane, (2-methylallyl)- (6CI);3-Cyclohexyl-2-methyl-1-propene; Methallylcyclohexane

Chemical Property of 3-CYCLOHEXYL-2-METHYL-1-PROPENE

Chemical Property:

• Vapor Pressure: 1.54mmHg at 25°C
• Refractive Index: 1.445
• Boiling Point: 175.4°C at 760 mmHg
• Flash Point: 46.9°C
• PSA: 0.00000
• Density: 0.804g/cm³
• LogP: 3.53290

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

3-Cyclohexyl-2-methyl-1-propene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-CYCLOHEXYL-2-METHYL-1-PROPENE

There total 6 articles about 3-CYCLOHEXYL-2-METHYL-1-PROPENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

1-bromocyclohexane (108-85-0) → (2-methylallyl)cyclohexane (3990-93-0)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); In toluene; at 80 ℃;

DOI:10.1016/S0040-4020(01)97185-6

Reference yield: 61.0%

2-methylprop-2-ene-1-sulfonyl chloride (14568-34-4) + cyclohexylmagnesiumchloride (931-51-1) → cyclohexylcyclohexane (92-51-3) + (2-methylallyl)cyclohexane (3990-93-0)

Guidance literature:

With iron(III) acetylacetonate; In tetrahydrofuran; diethyl ether; at 25 ℃; for 6h; Inert atmosphere;

DOI:10.1002/ejoc.200900927

Reference yield:

2-methyl-3-prop-2-enyl phenylselenide (59085-70-0) → di(2-methylallyl) selenide + 2,5-dimethyl-1,5-hexadiene (627-58-7) + (2-methylallyl)cyclohexane (3990-93-0) + isobutene (115-11-7,15220-85-6)

Guidance literature:

In cyclohexane; at 20 ℃; Further Variations:; reaction times; Product distribution; Photolysis;

DOI:10.1021/jo701447a

upstream raw materials:

2-methyl-3-bromo-1-propene

Cyclohexyl iodide

1-bromocyclohexane

3-Chloro-2-methylpropene

Downstream raw materials:

1-Brom-2-methyl-3-cyclohexylpropen

2-Methyl-2-cyclohexylmethyl-cyclopropancarbonsaeure