trans-Mn(CO)4(PPh₃)BF₄

Base Information

Chemical Name:trans-Mn(CO)4(PPh₃)BF₄
CAS No.:118228-16-3
Molecular Formula:BF₄*C₄₀H₃₀MnO₄P₂
Molecular Weight:778.366
Hs Code.:

trans-Mn(CO)4(PPh<sub>3</sub>)BF<sub>4</sub>

Synonyms:trans-Mn(CO)4(PPh₃)BF₄

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Chemical Property of trans-Mn(CO)4(PPh₃)BF₄

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Technology Process of trans-Mn(CO)4(PPh₃)BF₄

There total 1 articles about trans-Mn(CO)4(PPh₃)BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 14104-20-2
silver tetrafluoroborate

: 15662-31-4
mer,trans-BrMn(CO)3(PPh₃)2

: 118228-16-3
trans-Mn(CO)4(PPh₃)BF₄

Guidance literature:: With carbon monoxide; In dichloromethane; refluxing soln. of mer,trans-BrMn(CO)4PPh3 while bubbling CO through soln., addn. of AgBF4 during 30 min., cooling to room temp.; filtration through Celite, addn. of ether and cooling to 0 °C, pptn.; react. monitored by IR, elem. anal.;

Reference yield: 97.0%

: 118228-16-3
trans-Mn(CO)4(PPh₃)BF₄

: tetraethylammonium borohydride

: 110351-58-1
mer,trans-Mn(CO)3(PPh₃)2CHO

Guidance literature:: In methanol; acetonitrile; addn. of Et4NBH4 to stirred soln. of Mn(CO)4(PPh3)2BF4 at 0 ° C under N2, react. complete and pptn. after 2 min.; transfer of mixture to low-temp. crystallizer maintained at 0 °C under N2, collection of ppt. on the frit, washing with cold CH3CN/MeOH, drying in vacuo ; elem. anal.;

Reference yield: 65.0%

: 118228-16-3,20566-59-0
[Mn(CO)4(P(C₆H₅)3)2]⁽¹⁺⁾*BF₄^(1-)=[Mn(CO)4(P(C₆H₅)3)2][BF₄]

: 1109-15-5
tris(pentafluorophenyl)borate

: sodium triethylborohydride

: [Mn(CO)3(P(C₆H₅)3)2(CHOB(C₆F₅)3)]

Guidance literature:: In toluene; byproducts: NaBF4, BEt3; (N2); std. Schlenk technique; NaHBEt3 (1 equiv.) in toluene was syringedto stirred suspn. of Mn complex in THF; filtered; soln. of B compd. in toluene was added; stirred for 5 min; evapd.; recrystd. (CH2Cl2/petroleum ether); dried (vac.); elem. anal.;
DOI:10.1021/om900804j