Ethylenediamine diacetate

Base Information

• Chemical Name: Ethylenediamine diacetate
• CAS No.: 38734-69-9
• Molecular Formula: C6H16N2O4
• Molecular Weight: 180.204
• Hs Code.: 2923900090
• DSSTox Substance ID: DTXSID10436235
• Mol file: 38734-69-9.mol

Synonyms:Ethylenediamine diacetate;38734-69-9;Ethane-1,2-diamine diacetate;acetic acid;ethane-1,2-diamine;1,2-Ethanediamine, acetate (1:2);1,2-Ethanediamine, diacetate;MFCD00192147;Ethane-1,2-diaminediacetate;SCHEMBL26819;Ethylenediamine diacetate, 98%;DTXSID10436235;SAXQBSJDTDGBHS-UHFFFAOYSA-N;AKOS025295272;CS-0452080;F71640;Ethylenediamine diacetate 420352_ALDRICH 03572_FLUKA MolPort-003-925-310 CID10154317 IUPAC: Acetic Acid

Chemical Property of Ethylenediamine diacetate

Chemical Property:

• Vapor Pressure: 15.8mmHg at 25°C
• Melting Point: 118-120 °C(lit.)
• Boiling Point: 119.7°C at 760 mmHg
• Flash Point: 33.9°C
• PSA: 126.64000
• LogP: 0.48620
• Storage Temp.: -20°C Freezer
• Solubility.: Chloroform; Dichloromethane; Ethyl Acetate; Toluene
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 180.11100700
• Heavy Atom Count: 12
• Complexity: 37

Purity/Quality:

98%,99%, ^*data from raw suppliers

EthanediammoniumDiacetate ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)O.CC(=O)O.C(CN)N
• Uses: 1,2-Ethanediamine, acetate (1:2) is used as a catalyst for the preparation of various organic compounds such as methanodibenzodioxocin flavonoids, and chromeno-?annulated cis-?fused pyrano[3,?4-?c]?benzopyran. It is also useful reagent for the synthesis of organic compunds such as arylmethyl nitrodihydroimidazopyridinium.

Technology Process of Ethylenediamine diacetate

There total 3 articles about Ethylenediamine diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

acetic acid (64-19-7,77671-22-8) + ethylenediamine (107-15-3,85404-18-8) → ethylenediamine diacetic acid (38734-69-9)

Guidance literature:

In diethyl ether; at 4 ℃; for 14h;

DOI:10.15227/orgsyn.069.0031

Reference yield:

acetic acid (64-19-7,77671-22-8) + ethylenediamine (107-15-3,85404-18-8) → ethylenediamine monoacetic acid (38734-69-9,41033-95-8,56585-42-3,56585-43-4)

Guidance literature:

In ethanol; water;

DOI:10.1002/cctc.201800040

Reference yield:

→ ethylenediamine monoacetic acid (38734-69-9,41033-95-8,56585-42-3,56585-43-4)

Guidance literature:

upstream raw materials:

acetic acid

ethylenediamine

Downstream raw materials:

2,3-diphenylpyrazine

1,8-diphenyl-3,6-diazatricyclo<4.3.1.1^3,8>undecan-9-one

Refernces

• 1、 -. "With fluorescence of a process for the preparation of carboxylic acid ammonium salt (by machine translation)". Paragraph 0041; 0042. . Retrieved 2016/10/20.
• 2、 Tietze,Kiedrowski,Fahlbusch,Voss. "Diasteroselective formation of α-methoxycarbonyl lactones through an intramolecular Diels-Alder reaction: (4RS,4aRS,6RS,8aRS)-, (4S,4aS,6S,8aS)- and (4R,4aR,6R,8aR)-4-methoxycarbonyl-1,1,6-trimethyl-1,4,4A,5,6,7,8,8a-octahydro-2,3-benzopyrone [rac-5, (+)-". . p. 31 - 31. Retrieved 2017/06/01.