2,2',2''-tris<(pentafluorophenyl)amino>triethylamine

Base Information

• Chemical Name: 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine
• CAS No.: 155019-77-5
• Molecular Formula: C₂₄H₁₅F₁₅N₄
• Molecular Weight: 644.386
• Mol file: 155019-77-5.mol

Synonyms:2,2',2''-tris<(pentafluorophenyl)amino>triethylamine

Chemical Property of 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine

There total 1 articles about 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Hexafluorobenzene (392-56-3) + 2,2',2''-triaminotriethylamine (4097-89-6) → 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine (155019-77-5)

Guidance literature:

With potassium carbonate; In dimethyl sulfoxide; at 70 ℃; for 24h;

DOI:10.1021/ja00089a028

Reference yield: 85.0%

tetrachlorobis(tetrahydrofurano)molybdenum(IV) (16998-75-7) + 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine (155019-77-5) → Mo(N(CH2CH2NC6F5)3)Cl (155019-63-9)

Guidance literature:

With N(C₂H₅)3; In tetrahydrofuran; under exclusion of air; a soln. of the amine and Et3N in THF was added to a suspn. of the Mo compd., stirred at room temp. for 3 h; filtered, extd. with THF, solvent was removed in vac., taken up in 1,2-dimethoxyethane, filtered, solvent was removed in vac., washed with pentane, recrystd. from THF-ether; elem. anal.;

DOI:10.1021/ja00089a028

Reference yield: 83.3%

trimethylsilylazide (4648-54-8) + V(N(SiMe3)2)3 + 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine (155019-77-5) → C27H21F15N5SiV

Guidance literature:

V(N(SiMe₃)2)3; 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine; In tetrahydrofuran; at 70 ℃; for 3h; Inert atmosphere;

trimethylsilylazide; In tetrahydrofuran; at 70 ℃; for 5h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.0c01464

upstream raw materials:

Hexafluorobenzene

2,2',2''-triaminotriethylamine

Downstream raw materials:

W(N(CH₂CH₂NC₆F₅)3)Cl

Mo(N(CH₂CH₂NC₆F₅)3)Cl

Mo(N(CH₂CH₂NC₆F₅)3)(N(CH₃)2)

[Fe(N(C₂H₄NC₆F₅)3)]

Refernces