1,1'-Biphenyl, 4-cyclohexyl-

Base Information

• Chemical Name: 1,1'-Biphenyl, 4-cyclohexyl-
• CAS No.: 3842-58-8
• Deprecated CAS: 12710-24-6,39278-87-0,39346-75-3
• Molecular Formula: C18H20
• Molecular Weight: 236.357
• Hs Code.: 2902909090
• UNII: AL4V9L11ZP
• DSSTox Substance ID: DTXSID4073332
• Nikkaji Number: J632.176C
• Wikidata: Q27273976
• Mol file: 3842-58-8.mol

Synonyms:1,1'-Biphenyl, 4-cyclohexyl-;4-cyclohexylbiphenyl;3842-58-8;1-cyclohexyl-4-phenylbenzene;p-cyclohexylbiphenyl;Santicizer HB 40;AL4V9L11ZP;UNII-AL4V9L11ZP;1,1'-Biphenyl, cyclohexyl-;1-CYCLOHEXYL-4-PHENYL-BENZENE;P-PHENYLCYCLOHEXYLBENZENE;DTXSID4073332;BSHSCWRTJSBWLY-UHFFFAOYSA-N;4-CYCLOHEXYL-1,1'-BIPHENYL;cyclohexane, [1,1'-biphenyl]-4-yl-;39346-75-3;Q27273976;12710-24-6

Chemical Property of 1,1'-Biphenyl, 4-cyclohexyl-

Chemical Property:

• Melting Point: 74.5 °C
• Boiling Point: 366.3°Cat760mmHg
• Flash Point: 189.4°C
• PSA: 0.00000
• Density: 1.001g/cm³
• LogP: 5.40130
• XLogP3: 6.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 236.156500638
• Heavy Atom Count: 18
• Complexity: 224

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)C2=CC=C(C=C2)C3=CC=CC=C3

Technology Process of 1,1'-Biphenyl, 4-cyclohexyl-

There total 38 articles about 1,1'-Biphenyl, 4-cyclohexyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-bromocyclohexane (108-85-0) + 4-bromo-1,1'-biphenyl (92-66-0) → 4-cyclohexylbiphenyl (3842-58-8,39346-75-3)

Guidance literature:

With potassium hexafluorophosphate; bis(1,3-bis((4-methyl-2-pyridyl)imino)isoindolinato)nickel(II); C₂₂H₁₉N₅NiO₂; In N,N-dimethyl acetamide; at 20 ℃; Inert atmosphere; Electrolysis; Sealed tube;

DOI:10.1021/jacs.0c01475

Reference yield: 96.0%

4-iodo-biphenyl (1591-31-7) + 1-cyclohexyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate salt → 2,4,6-triphenylpyridine (580-35-8) + 4-cyclohexylbiphenyl (3842-58-8,39346-75-3)

Guidance literature:

With [2,2]bipyridinyl; manganese; (1,2-dimethoxyethane)dichloronickel(II); In N,N-dimethyl acetamide; at 20 ℃;

DOI:10.1039/c9sc00783k

Reference yield: 95.0%

4-iodo-biphenyl (1591-31-7) + 1-cyclohexyl-2,4,6-triphenylpyridin-1-ium tetrafluoroborate salt → 4-cyclohexylbiphenyl (3842-58-8,39346-75-3)

Guidance literature:

With manganese; (1,2-dimethoxyethane)dichloronickel(II); In N,N-dimethyl acetamide;

DOI:10.1039/c9sc00783k

upstream raw materials:

1-bromocyclohexane

biphenyl

Cyclohexyl benzenesulphonate

cyclohexene

Downstream raw materials:

4,4'-Dicyclohexyl-biphenyl

[1,1';4',1'']terphenyl

terephthalic acid

4-bromo-p-terphenyl