bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

Base Information

Chemical Name:bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron
CAS No.:1616135-83-1
Molecular Formula:C₅₉H₆₁BO₄
Molecular Weight:844.942
Hs Code.:

Synonyms:bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

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Chemical Property of bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

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Technology Process of bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

There total 5 articles about bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 1616135-82-0
2-((6-bromo-pyrene-1-yl)methoxy)tetrahydro-2H-pyran

: 145434-22-6
2,4,6-triisopropylphenylboronic acid dimethyl ester

: 1616135-83-1
bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

Guidance literature:: 2-((6-bromo-pyrene-1-yl)methoxy)tetrahydro-2H-pyran; With n-butyllithium; In diethyl ether; hexane; at -78 - 20 ℃; for 3h; Inert atmosphere;

2,4,6-triisopropylphenylboronic acid dimethyl ester; In diethyl ether; hexane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201403918

Reference yield:

: 6-bromo-pyrene-1-carbaldehyde

: 1616135-83-1
bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium tetrahydroborate / tetrahydrofuran / 3 h / 20 °C / Cooling with ice

2.1: pyridinium p-toluenesulfonate / dichloromethane / 6 h / 20 °C

3.1: n-butyllithium / diethyl ether / 2 h / 20 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

With sodium tetrahydroborate; n-butyllithium; pyridinium p-toluenesulfonate; In tetrahydrofuran; diethyl ether; dichloromethane;

Reference yield:

: 1714-29-0
1-bromopyrene

: 1616135-83-1
bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

Guidance literature:: Multi-step reaction with 4 steps

1.1: titanium tetrachloride / dichloromethane / 3 h / 20 °C / Cooling with ice

2.1: sodium tetrahydroborate / tetrahydrofuran / 3 h / 20 °C / Cooling with ice

3.1: pyridinium p-toluenesulfonate / dichloromethane / 6 h / 20 °C

4.1: n-butyllithium / diethyl ether / 2 h / 20 °C / Inert atmosphere

4.2: 20 °C / Inert atmosphere

With sodium tetrahydroborate; n-butyllithium; pyridinium p-toluenesulfonate; titanium tetrachloride; In tetrahydrofuran; diethyl ether; dichloromethane;