Dimethyl (2,4,6-triisopropylphenyl)boronate

Base Information

• Chemical Name: Dimethyl (2,4,6-triisopropylphenyl)boronate
• CAS No.: 145434-22-6
• Molecular Formula: C17H29 B O2
• Molecular Weight: 276.227
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID60448949
• Nikkaji Number: J1.003.713A
• Wikidata: Q82268178
• Mol file: 145434-22-6.mol

Synonyms:145434-22-6;Dimethyl (2,4,6-triisopropylphenyl)boronate;2,4,6-Triisopropylphenylboronic acid methyl ester;dimethoxy-[2,4,6-tri(propan-2-yl)phenyl]borane;(2,4,6-Triisopropylphenyl)dimethoxyboron;Boronic acid, B-[2,4,6-tris(1-methylethyl)phenyl]-, dimethyl ester;2,4,6-Triisopropylphenylboronic acid met;Dimethyl(2,4,6-triisopropylphenyl)boronate;SCHEMBL5506707;DTXSID60448949;KRQWDHHDTSORLQ-UHFFFAOYSA-N;Boronic acid, [2,4,6-tris(1-methylethyl)phenyl]-, dimethyl ester;AKOS015999796;(2,4,6-triisopropylphenyl)dimethoxyborane;CS-0337204;F71679;A884621;Dimethyl [2,4,6-tri(propan-2-yl)phenyl]boronate;2,4,6-Triisopropylphenylboronic acid methyl ester, 96%;Boronicacid,B-[2,4,6-tris(1-methylethyl)phenyl]-,dimethylester

Chemical Property of Dimethyl (2,4,6-triisopropylphenyl)boronate

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: n20/D 1.484
• Boiling Point: 323.448°C at 760 mmHg
• Flash Point: 110 °C
• PSA: 18.46000
• Density: 0.913 g/mL at 25 °C
• LogP: 4.04480
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 276.2260603
• Heavy Atom Count: 20
• Complexity: 256

Purity/Quality:

97% ^*data from raw suppliers

2,4,6-Triisopropylphenylboronic acid methyl ester 96% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=C(C=C(C=C1C(C)C)C(C)C)C(C)C)(OC)OC

Technology Process of Dimethyl (2,4,6-triisopropylphenyl)boronate

There total 3 articles about Dimethyl (2,4,6-triisopropylphenyl)boronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Trimethyl borate (121-43-7,63156-11-6) + (2,4,6-triisopropylphenyl)magnesium bromide (108894-99-1) → 2,4,6-triisopropylphenylboronic acid dimethyl ester (145434-22-6)

Guidance literature:

Reference yield: 74.0%

Trimethyl borate (121-43-7,63156-11-6) + 2,4,6-triisopropyl-1-bromobenzene (21524-34-5) → 2,4,6-triisopropylphenylboronic acid dimethyl ester (145434-22-6)

Guidance literature:

2,4,6-triisopropyl-1-bromobenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 16h;

Reference yield:

C13H13BBrNO2 + (2,4,6-triisopropylphenyl)magnesium bromide (108894-99-1) → 1,3,5-triisopropyl benzene (717-74-8) + C27H33BBrNO + 2,4,6-triisopropylphenylboronic acid dimethyl ester (145434-22-6)

Guidance literature:

In tetrahydrofuran; at 0 - 75 ℃; for 9h; Inert atmosphere;

DOI:10.1039/d0dt03619f

upstream raw materials:

Trimethyl borate

(2,4,6-triisopropylphenyl)magnesium bromide

2,4,6-triisopropyl-1-bromobenzene

Downstream raw materials:

3,7-dibromo dibenzoborole

dipyren-1-yl(2,4,6-triisopropylphenyl)borane

bis(6-((tetrahydro-2H-pyran-2-yloxy)methyl)pyrene-1-yl)(2,4,6-triisopropyl-phenyl)boron

5-(2,4,6-tri-iso-propylphenyl)-5H-dibenzo[b,f]borepin