C-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl) formamide

Base Information

Chemical Name:C-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl) formamide
CAS No.:286369-06-0
Molecular Formula:C35H29 N O10
Molecular Weight:623.616
Hs Code.:
DSSTox Substance ID:DTXSID401166819
Nikkaji Number:J1.274.728D
Mol file:286369-06-0.mol

Synonyms:286369-06-0;DTXSID401166819;C-(2,3,4,6-TETRA-O-BENZOYL-BETA-D-GLUCOPYRANOSYL) FORMAMIDE;c-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl)formamide;(2-O,3-O,4-O,6-O-Tetrabenzoyl-beta-D-glucopyranosyl)formamide;D-glycero-D-gulo-Heptonamide, 2,6-anhydro-, 3,4,5,7-tetrabenzoate

Suppliers and Price of C-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl) formamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
C-(2,3,4,6-TETRA-O-BENZOYL-BETA-D-GLUCOPYRANOSYL) FORMAMIDE 95.00%
5MG
$ 498.42

Total 3 raw suppliers

Chemical Property of C-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl) formamide

Chemical Property:

Boiling Point:803.6±65.0 °C(Predicted)
PKA:14.98±0.70(Predicted)
PSA：157.52000
Density:1.39±0.1 g/cm3(Predicted)
LogP:4.47320
XLogP3:5.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:14
Exact Mass:623.17914612
Heavy Atom Count:46
Complexity:1060

Purity/Quality:

97% ^*data from raw suppliers

C-(2,3,4,6-TETRA-O-BENZOYL-BETA-D-GLUCOPYRANOSYL) FORMAMIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C(=O)OCC2C(C(C(C(O2)C(=O)N)OC(=O)C3=CC=CC=C3)OC(=O)C4=CC=CC=C4)OC(=O)C5=CC=CC=C5
Isomeric SMILES:C1=CC=C(C=C1)C(=O)OC[C@@H]2[C@H]([C@@H]([C@H]([C@@H](O2)C(=O)N)OC(=O)C3=CC=CC=C3)OC(=O)C4=CC=CC=C4)OC(=O)C5=CC=CC=C5

Technology Process of C-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl) formamide

There total 3 articles about C-(2,3,4,6-Tetra-O-benzoyl-beta-D-glucopyranosyl) formamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 286369-05-9
2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl cyanide

: 286369-06-0
2,6-anhydro-3,4,5,7-tetra-O-benzoyl-D-glycero-D-gulo-heptonamide

Guidance literature:: With hydrogen bromide; acetic acid; at 20 ℃;
DOI:10.1016/S0957-4166(99)00486-3

Reference yield: 39.0%

: N-acetyl-C-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)formamide

: 67-64-1
acetone

: acetone N²-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosylcarbonyl)hydrazone

: 286369-06-0
2,6-anhydro-3,4,5,7-tetra-O-benzoyl-D-glycero-D-gulo-heptonamide

Guidance literature:: N-acetyl-C-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)formamide; With hydrazine hydrate; In pyridine; at 20 ℃; for 3h;

acetone; With silica gel; In hexane; at 20 ℃;
DOI:10.1016/j.tet.2017.05.014

Reference yield:

: 14218-11-2
2,3,4,6-tetra-O-benzoylglucosyl bromide

: 286369-06-0
2,6-anhydro-3,4,5,7-tetra-O-benzoyl-D-glycero-D-gulo-heptonamide

Guidance literature:: Multi-step reaction with 2 steps

1: 58 percent / nitromethane / 20 °C

2: 94 percent / HBr; acetic acid / 20 °C

With hydrogen bromide; acetic acid; In nitromethane; 1: Substitution / 2: Hydrolysis;
DOI:10.1016/S0957-4166(99)00486-3