3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

Base Information

Chemical Name:3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane
CAS No.:548458-84-0
Molecular Formula:C₂₅H₂₉NO₃
Molecular Weight:391.51
Hs Code.:

Synonyms:3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

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Chemical Property of 3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

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Technology Process of 3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

There total 5 articles about 3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 90-99-3
diphenylchloromethane

: 548458-83-9
8-ethoxycarbonyl-3-hydroxymethylmethylidenyl-8-azabicyclo[3.2.1]octane

: 548458-84-0
3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

Guidance literature:: at 145 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.bmc.2011.10.028

Reference yield:

: 32499-64-2
N-carbethoxytropinone

: 548458-84-0
3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / DBU; LiCl / acetonitrile / 25 °C

2: 86 percent / LiAlH₄ / tetrahydrofuran / 0 °C

3: 145 °C

With lithium aluminium tetrahydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; In tetrahydrofuran; acetonitrile;
DOI:10.1016/S0960-894X(02)01051-X

Reference yield:

: 532-24-1
tropinone

: 548458-84-0
3-(2-(diphenylmethoxy)ethylidenyl)-8-ethoxycarbonyl-8-azabicyclo[3.2.1]octane

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / K₂CO₃ / toluene / Heating

2: 80 percent / DBU; LiCl / acetonitrile / 25 °C

3: 86 percent / LiAlH₄ / tetrahydrofuran / 0 °C

4: 145 °C

With lithium aluminium tetrahydride; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; In tetrahydrofuran; toluene; acetonitrile;
DOI:10.1016/S0960-894X(02)01051-X