4-Iodotetrahydrothiopyran

Base Information

Chemical Name:4-Iodotetrahydrothiopyran
CAS No.:281204-90-8
Molecular Formula:C₅H₉IS
Molecular Weight:228.097
Hs Code.:
European Community (EC) Number:886-585-0
DSSTox Substance ID:DTXSID70594663
Wikidata:Q82489571
Mol file:281204-90-8.mol

Synonyms:4-iodotetrahydrothiopyran;281204-90-8;4-iodothiane;4-iodotetrahydro-2H-thiopyran;Tetrahydro-4-iodo-2H-thiopyran;MFCD09025908;SCHEMBL1770706;DTXSID70594663;JVBIONNYIWEILC-UHFFFAOYSA-N;BS-28106;SY318977;DB-067876;CS-0045981;G37520;EN300-7367576

Suppliers and Price of 4-Iodotetrahydrothiopyran

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
4-IODOTETRAHYDROTHIOPYRAN 95.00%
1G
$ 947.16

Total 8 raw suppliers

Chemical Property of 4-Iodotetrahydrothiopyran

Chemical Property:

Vapor Pressure:0.0433mmHg at 25°C
Refractive Index:1.61
Boiling Point:246.1°Cat760mmHg
Flash Point:102.7°C
Density:1.79g/cm³
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:227.94697
Heavy Atom Count:7
Complexity:50

Purity/Quality:

98%min ^*data from raw suppliers

4-IODOTETRAHYDROTHIOPYRAN 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CSCCC1I

Technology Process of 4-Iodotetrahydrothiopyran

There total 2 articles about 4-Iodotetrahydrothiopyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 29683-23-6
tetrahydrothiopyran-4-ol

: 281204-90-8
4-iodotetrahydro-2H-thiopyran

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In dichloromethane; at 0 - 20 ℃; for 16h; Inert atmosphere;
DOI:10.1021/jacs.1c12649

Reference yield:

: 1072-72-6
Tetrahydrothiopyran-4-one

: 281204-90-8
4-iodotetrahydro-2H-thiopyran

Guidance literature:: Multi-step reaction with 2 steps

1: methanol; sodium tetrahydroborate / 1 h / 0 - 20 °C

2: 1H-imidazole; triphenylphosphine; iodine / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; methanol; sodium tetrahydroborate; iodine; triphenylphosphine; In dichloromethane;

Reference yield: 73.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 281204-90-8
4-iodotetrahydro-2H-thiopyran

: 100277-27-8
(tetrahydro-2H-thiopyran-4-yl)methanol

Guidance literature:: With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; N-ethyl-N,N-diisopropylamine; In water; acetonitrile; at 20 ℃; for 16h; Irradiation;
DOI:10.1039/d1sc03083c