2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide

Base Information

• Chemical Name: 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide
• CAS No.: 919081-07-5
• Molecular Formula: C₉H₁₁BrSSe
• Molecular Weight: 310.116
• Mol file: 919081-07-5.mol

Synonyms:2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide

Chemical Property of 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide

There total 1 articles about 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

C9H12SSe2 → 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide (919081-07-5)

Guidance literature:

With bromine; In tetrachloromethane; diethyl ether; at 0 ℃; for 0.5h;

DOI:10.1002/ejoc.200600517

Reference yield:

2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide (919081-07-5) + styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → 1-{[(2R)-2-azido-2-phenylethyl]selenenyl}-2-[(1S)-1-(methylthio)ethyl]benzene + C17H19N3SSe

Guidance literature:

With sodium azide; In acetonitrile; at 20 ℃; for 72h;

DOI:10.1002/ejoc.200600517

Reference yield:

2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide (919081-07-5) + styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → (1R)-2-{2-[(1S)-1-(methylthio)ethyl]phenylselenenyl}-1-phenylethanol (919081-20-2) + (S)-2-[2-((S)-1-Methylsulfanyl-ethyl)-phenylselanyl]-1-phenyl-ethanol

Guidance literature:

With water; In acetonitrile; at -30 ℃; for 72h;

DOI:10.1002/ejoc.200600517

Downstream raw materials:

(1R)-2-{2-[(1S)-1-(methylthio)ethyl]phenylselenenyl}-1-phenylethanol