919081-20-2

Upstream product

• 100-42-5 styrene 
• 278790-75-3 C₁₀H₁₁F₃O₃S₂Se 
• 919081-07-5 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl bromide 
• 919081-09-7 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl chloride 
• 919081-11-1 2-{[(1S)-1-methylthio]-ethyl}phenylselenenyl iodide 

Downstream Products

• 1445-91-6 (S)-1-phenylethanol 

Relevant academic research and scientific papers

Intramolecular nonbonding interactions between selenium and sulfur - Spectroscopic evidence and importance in asymmetric synthesis

Chiral sulfur-containing electrophilic selenium reagents can be employed to effect efficient asymmetric syntheses. Spectroscopic and chemical evidence demonstrate that the observed high selectivity of the asymmetric reactions is associated with a nonbondi

Efficient asymmetric selenomethoxylation and selenohydroxylation of alkenes with a new sulfur containing chiral diselenide

The synthesis of a new chiral non-racemic sulfur containing diselenide is described. The electrophilic selenium reagent, produced from this diselenide by treatment with bromine and silver triflate, has been used to effect the selenomethoxylation and the selenohydroxylation of alkenes. These addition reactions occurred with good chemical yield and with high diastereoselectivities. (C) 2000 Elsevier Science Ltd.