cis-[PtCl₂(Ph₂P(CH₂)2Si(OEt)3)2]

Base Information

• Chemical Name: cis-[PtCl₂(Ph₂P(CH₂)2Si(OEt)3)2]
• CAS No.: 79919-60-1
• Molecular Formula: C₄₀H₅₈Cl₂O₆P₂PtSi₂
• Molecular Weight: 1019
• Mol file: 79919-60-1.mol

Synonyms:cis-[PtCl₂(Ph₂P(CH₂)2Si(OEt)3)2]

Chemical Property of cis-[PtCl₂(Ph₂P(CH₂)2Si(OEt)3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis-[PtCl₂(Ph₂P(CH₂)2Si(OEt)3)2]

There total 2 articles about cis-[PtCl₂(Ph₂P(CH₂)2Si(OEt)3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + (trisethoxysilyl)ethyldiphenylphosphine (18586-39-5) → cis-[PtCl2(Ph2P(CH2)2Si(OEt)3)2] (79919-60-1)

Guidance literature:

With pentane; In toluene; (Ar), addition (pentane); washing (pentane);

DOI:10.1006/jcat.1998.2151

Reference yield:

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + (trisethoxysilyl)ethyldiphenylphosphine (18586-39-5) → cis-[PtCl2(Ph2P(CH2)2Si(OEt)3)2] (79919-60-1) + trans-[PtCl2(Ph2P(CH2)2Si(OEt)3)2] (79980-82-8)

Guidance literature:

In benzene; in an inert atmosphere using standard vacuum line technique; cis isomer was obtained by reducing the volume of the soln. and allowing to ppt., complete removal of the solvent in vac., crystd. upon treatment with hexane, this product was mixture of cis and trans isomers; identified by 31P NMR spectra;

DOI:10.1021/ja00366a011

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

(trisethoxysilyl)ethyldiphenylphosphine

dichloro(1,5-cyclooctadiene)platinum(ll)