[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)]

Base Information

• Chemical Name: [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)]
• CAS No.: 691410-55-6
• Molecular Formula: C₃₈H₃₂MoO₃P₂Ru
• Molecular Weight: 795.628
• Mol file: 691410-55-6.mol

Synonyms:[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)]

Chemical Property of [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)]

There total 5 articles about [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium (71397-33-6) + Na[CpMo(CO)3] (12107-35-6) → [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)] (691410-55-6)

Guidance literature:

In tetrahydrofuran; (N2); THF added to a solid mixt. of complexes, heated at 120°C for 48 h; filtration, concn. (vac.), addn. of hexane, stirring, filtration, washing (MeOH, Et2O), drying (vac.); elem. anal.;

DOI:10.1039/b306835h

Reference yield:

[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-H)Mo(CO)2(η5-C5H5)][Cl] (691410-59-0) + sodium tetraphenyl borate (143-66-8) → [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)] (691410-55-6) + triphenylborane (960-71-4)

Guidance literature:

In tetrahydrofuran-d8; byproducts: C6H6; (N2); heated at 95°C for 4 h in a NMR tube; not isolated, detected by NMR;

DOI:10.1039/b306835h

Reference yield:

[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-H)Mo(CO)2(η5-C5H5)][Cl] (691410-59-0) → [(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)Mo(CO)2(η5-C5H5)] (691410-55-6)

Guidance literature:

With Et₃SiH; In tetrahydrofuran-d8; byproducts: chlorotriethylsilane, H2; (N2); refluxed for 24 h in a NMR tube; not isolated, detected by NMR;

DOI:10.1039/b306835h

upstream raw materials:

chloro(cyclopentadienyl)[bis(diphenylphosphino)methane]ruthenium

Na[CpMo(CO)3]

[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-H)Mo(CO)2(η5-C5H5)][Cl]

sodium tetraphenyl borate

Downstream raw materials:

[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-H)Mo(CO)2(η5-C5H5)][Cl]

[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-H)Mo(CO)2(η5-C5H5)][OTf]

[(η5-C5H5)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-H)Mo(CO)2(η5-C5H5)][BF4]