mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

Base Information

Chemical Name:mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]
CAS No.:1152333-09-9
Molecular Formula:C₅₈H₅₁N₂P₃RuS
Molecular Weight:1002.11
Hs Code.:

Synonyms:mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

Suppliers and Price of mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

Chemical Property:

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Technology Process of mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

There total 2 articles about mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 55102-19-7
hydridochlorotris(triphenylphosphine)ruthenium(II)

: 60-56-0
2-Mercapto-1-methylimidazole

: 1152333-09-9
mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

Guidance literature:: With CH₃CH₂CH₂CH₂Li; In tetrahydrofuran; hexane; (inert atm., Schlenk technique); addn. of hexane soln. of butyllithium to THF soln. of imidazole deriv. at room temp., stirring at room temp. for 5 min, addn. to suspn. of ruthenium compd. in THF, stirring at 60°C for 4 h; filtration, washing with ethanol and petroleum ether, drying in vac., recrystn. (CH2Cl2/petroleum or ethanol), elem. anal.;
DOI:10.1021/om900157b

Reference yield:

: [RuH(κ3-H,S,S-hydridotris(methimazolyl)borate)(PPh3)2]*toluene

: 1152333-09-9
mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

Guidance literature:: In methanol; dichloromethane; (inert atm., Schlenk technique); recrystn. (CH2Cl2/methanol) for 2 ds; isolation of crystals, X-ray anal.;
DOI:10.1021/om900157b

Reference yield:

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 1152333-09-9
mer-[RuH(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)2]

: 1152333-13-5
mer-[Ru(H2)(κ2-N,S-N-methyl-2-mercaptoimidazolate)(PPh3)3]BF4

Guidance literature:: In dichloromethane-d2; (Ar, Schlenk technique); addn. of tetrafluoroboronic acid to CD2Cl2 soln. of ruthenium compd. at -196°C, warming to 0°C; NMR monitoring;
DOI:10.1021/om900157b