cis-(Os(bpy)2(BPE)Cl)PF₆

Base Information

• Chemical Name: cis-(Os(bpy)2(BPE)Cl)PF₆
• CAS No.: 85661-67-2
• Molecular Formula: C₃₂H₂₆ClN₆Os*F₆P
• Molecular Weight: 865.216
• Mol file: 85661-67-2.mol

Synonyms:cis-(Os(bpy)2(BPE)Cl)PF₆

Chemical Property of cis-(Os(bpy)2(BPE)Cl)PF₆

Chemical Property:

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Technology Process of cis-(Os(bpy)2(BPE)Cl)PF₆

There total 1 articles about cis-(Os(bpy)2(BPE)Cl)PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

ammonium hexafluorophosphate + cis-dichlorobis(2,2'-bipyridine)osmium(II) hydrate (79982-56-2) + trans-1,2-bis(4-pyridyl)ethylene (1135-32-6) → cis-(Os(bpy)2(BPE)Cl)PF6 (85661-67-2)

Guidance literature:

In ethanol; water; to N2-deoxygenated suspn. cis-Os(bipy)2Cl2*H2O in 1:1 water/ethanol excess BPE added and mixt. refluxed for 20 h, soln. reduced, filtered and extd. with ether, to aq. layer aq. NH4PF6 added; ppt. filtered, washed with water and ether and dried, solid purified bychromy. with 1:1 toluene/CH3CN as eluent, purple-red band collected, solvent removed, complex isolated by repptn. from CH2Cl2 into ether; elem.anal.;

upstream raw materials:

cis-dichlorobis(2,2'-bipyridine)osmium(II) hydrate

trans-1,2-bis(4-pyridyl)ethylene