(6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

Base Information

Chemical Name:(6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol
CAS No.:903558-97-4
Molecular Formula:C₃₅H₆₄O₅Si₂
Molecular Weight:621.061
Hs Code.:

Synonyms:(6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

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Chemical Property of (6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

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Technology Process of (6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

There total 6 articles about (6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 903558-96-3
(2S,4S,5R)-4-[(3E,6Z)-(1S,2S,5S)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-3,5-dimethyl-2-triethylsilanyloxy-octa-3,6-dienyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxane

: 903558-97-4
(6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 - 0 ℃;
DOI:10.1016/j.tetlet.2006.04.044

Reference yield:

: (E)-(2R,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-6-[(2S,4S,5R)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2,4-dimethyl-5-triethylsilanyloxy-hept-3-enal

: 903558-97-4
(6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: t-BuOK / tetrahydrofuran / 0 °C

1.2: tetrahydrofuran / -78 - 20 °C

2.1: 84 percent / DIBAL-H / CH₂Cl₂ / -78 - 0 °C

With potassium tert-butylate; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tetlet.2006.04.044

Reference yield:

: 903558-95-2
(E)-(2R,5S,6S)-7-(tert-Butyl-dimethyl-silanyloxy)-6-[(2S,4S,5R)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2,4-dimethyl-5-triethylsilanyloxy-hept-3-en-1-ol

: 903558-97-4
(6E,9Z)-(2R,3S,4S,5S,8S)-4-(tert-Butyl-dimethyl-silanyloxymethyl)-3-(4-methoxy-benzyloxy)-2,6,8-trimethyl-5-triethylsilanyloxy-undeca-6,9-dien-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: Dess-Martin reagent; pyridine / CH₂Cl₂ / 0 °C

2.1: t-BuOK / tetrahydrofuran / 0 °C

2.2: tetrahydrofuran / -78 - 20 °C

3.1: 84 percent / DIBAL-H / CH₂Cl₂ / -78 - 0 °C

With pyridine; potassium tert-butylate; diisobutylaluminium hydride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; 1.1: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2006.04.044