2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene

Base Information

• Chemical Name: 2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene
• CAS No.: 1046158-53-5
• Molecular Formula: C₁₇H₁₆F₂N₂
• Molecular Weight: 286.324
• Mol file: 1046158-53-5.mol

Synonyms:2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene

Chemical Property of 2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene

There total 1 articles about 2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

acetylacetone (123-54-6,81235-32-7) + 4-fluoroaniline (371-40-4) → 2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene (1046158-53-5)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; for 24h; Reflux; Dean-Stark;

DOI:10.1002/anie.201914603

Reference yield: 80.0%

2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene (1046158-53-5) + triethylaluminum (97-93-8) → [2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-pentene]AlEt2 (1046459-10-2)

Guidance literature:

In hexane; under Ar; soln. were mixed at 0°C with rapid stirring, then soln.stirred overnight at room temp.; soln. was filtered, filtrate concd. under vac. ppt. deposited after 24 hat -40°C; elem. anal.;

DOI:10.1039/b802638f

Reference yield: 68.0%

[scandium tris(trimethylsilylmethyl)(THF)2] (41705-65-1) + 2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-petene (1046158-53-5) → C29H45F2N2OScSi2

Guidance literature:

In hexane; at 25 ℃; for 2h;

DOI:10.1002/anie.201914603

upstream raw materials:

acetylacetone

4-fluoroaniline

Downstream raw materials:

[2-(4-fluorophenyl)amino-4-(4-fluorophenyl)imino-2-pentene]AlEt₂