2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

Base Information

Chemical Name:2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal
CAS No.:1427016-51-0
Molecular Formula:C₅₆H₅₆O₅S₂
Molecular Weight:873.19
Hs Code.:

Synonyms:2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

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Chemical Property of 2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

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Technology Process of 2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

There total 3 articles about 2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1427016-50-9
6-O-trityl-D-glucose propane-1,3-diyl dithioacetal

: 100-39-0
benzyl bromide

: 1427016-51-0
2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

Guidance literature:: 6-O-trityl-D-glucose propane-1,3-diyl dithioacetal; With sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 0.5h;

benzyl bromide; With tetra-(n-butyl)ammonium iodide; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; at 20 ℃;
DOI:10.1021/jo400130p

Reference yield:

: 2280-44-6
D-Glucose

: 1427016-51-0
2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

Guidance literature:: Multi-step reaction with 3 steps

1.1: hydrogenchloride; water / 20 °C

2.1: dmap / pyridine / 48 h / 35 °C

3.1: sodium hydride / tetrahydrofuran; mineral oil; N,N-dimethyl-formamide / 0.5 h / 20 °C

3.2: 20 °C

With hydrogenchloride; dmap; water; sodium hydride; In tetrahydrofuran; pyridine; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/jo400130p

Reference yield:

: 16792-48-6
D-glucose propane-1,3-diyl dithioacetal

: 1427016-51-0
2,3,4,5-tetra-O-benzyl-6-O-trityl-D-glucose propane-1,3-diyldithioacetal

Guidance literature:: Multi-step reaction with 2 steps

1.1: dmap / pyridine / 48 h / 35 °C

2.1: sodium hydride / tetrahydrofuran; mineral oil; N,N-dimethyl-formamide / 0.5 h / 20 °C

2.2: 20 °C

With dmap; sodium hydride; In tetrahydrofuran; pyridine; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/jo400130p