(2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

Base Information

Chemical Name:(2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol
CAS No.:960243-45-2
Molecular Formula:C₂₃H₃₁N₃O₃Si
Molecular Weight:425.603
Hs Code.:

Synonyms:(2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

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Chemical Property of (2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

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Technology Process of (2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

There total 4 articles about (2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 136144-58-6
(2S,3R)-1-O-(tert-Butyldiphenylsilyl)-3,4-O-isopropylidenebutane-1,2,3,4-tetrol

: 960243-45-2
(2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

Guidance literature:: (2S,3R)-1-O-(tert-Butyldiphenylsilyl)-3,4-O-isopropylidenebutane-1,2,3,4-tetrol; With 2,6-dimethylpyridine; trifluoromethylsulfonic anhydride; In dichloromethane; at -78 ℃;

With sodium azide; In N,N-dimethyl-formamide; at 0 - 20 ℃; Further stages.;
DOI:10.1016/j.tetlet.2007.09.098

Reference yield:

: 1202878-83-8
C₂₄H₃₁F₃O₆SSi

: 960243-45-2
(2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.09.022

Reference yield:

: 354556-06-2
(2S,3R)-3-azido-2-hydroxy-4-(tert-butyldiphenyl)silyloxybutyl acetate

: 960243-45-2
(2R,3S)-2-azido-1-O-(tert-butyldiphenylsilyl)-3,4-O-isopropylodenebutane-1,3,4-triol

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / K₂CO₃ / methanol; H₂O

2: CSA

With camphor-10-sulfonic acid; potassium carbonate; In methanol; water;
DOI:10.1016/S0957-4166(01)00099-4