Technology Process of (C5H5)Fe(C5H4C6H4CO(ZnN6C60H61))
There total 1 articles about (C5H5)Fe(C5H4C6H4CO(ZnN6C60H61)) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
pyridine; oxalyl dichloride;
In
dichloromethane; toluene;
(COCl)2 added to Na 4-ferrocenylbenzoate and Py in CH2Cl2, 13 h room temp., reflux 5 h, volatiles removed, residue dissolved in toluene, added to porph. and Py in toluene, 18 h, evapd., chromed., dissolved in CHCl3, Zn(OAc)2 in MeOH added, reflux 30 min; react. mixt. was cooled, wshed with water, dried over Na2SO4, solvent was evapd., chromy. on silica with CHCl3 as eluent, pptn. from CHCl3/MeOH;
DOI:10.1021/ja004123v
- Guidance literature:
-
With
pyridine; thionyl chloride; tetrabutyl ammonium fluoride;
In
tetrahydrofuran; toluene; benzene;
soln. porph. acid, SOCl2 and Py in benzene rexluxed 2 h under N2, volatiles removed, residue dissolved in toluene+Py, soln. ferrocene and aniline in toluene+Py added, stirred overnight room temp. under N2, chromed., dissolved in THF, Bu4NF in THF added; after stirring for 3.5 h at room temp. under N2 solvents were removed under reduced pressure, chromy., pptn. from CHCl3/MeCN;
DOI:10.1021/ja004123v
