(Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate

Base Information

• Chemical Name: (Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate
• CAS No.: 1025476-39-4
• Molecular Formula: C₁₃H₁₇NOS₂
• Molecular Weight: 267.416
• Mol file: 1025476-39-4.mol

Synonyms:(Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate

Chemical Property of (Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate

There total 1 articles about (Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl-dithiocarbamic acid ethyl ester (1950-20-5) + 1-bromoacetone (598-31-2) → (Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate (1025476-39-4)

Guidance literature:

With triethylamine; In acetone; at 20 ℃; for 0.5h;

DOI:10.1016/j.tetlet.2008.02.103

Reference yield: 69.0%

(Z)-ethyl 2-oxopropyl benzyldithioimidocarbonate (1025476-39-4) → rac-N-[(2Z)-5-methyl-1,3-oxathiolan-2-ylidene]phenylmethanamine (101835-25-0)

Guidance literature:

With potassium hydroxide; sodium tetrahydroborate; In methanol; at 0 - 60 ℃; for 2.5h;

DOI:10.1016/j.tetlet.2008.02.103

upstream raw materials:

benzyl-dithiocarbamic acid ethyl ester

1-bromoacetone

Downstream raw materials:

rac-N-[(2Z)-5-methyl-1,3-oxathiolan-2-ylidene]phenylmethanamine